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Dichlorido{N'-[1-(2-pyridin-2-yl)ethyl-idene]acetohydrazide-κN',O}copper(II).

Datta A, Das K, Jhou YM, Huang JH, Lee HM - Acta Crystallogr Sect E Struct Rep Online (2010)

Bottom Line: The chloride ligand in the axial position forms a long Cu-Cl distance of 2.4892 (9) Å.In contrast, the Cu-Cl distance from the equatorial chloride ligand is much shorter [2.2110 (7) Å].Inter-molecular N-H⋯Cl and C-H⋯Cl hydrogen bonds link the complexes into a three-dimensional network.

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Affiliation: National Changhua University of Education, Department of Chemistry, Changhua, Taiwan 50058.

ABSTRACT
In the title compound, [CuCl(2)(C(9)H(11)N(3)O)], the Cu(II) atom is in a distorted square-pyramidal CuCl(2)N(2)O coordination geometry. The tridentate acetohydrazide ligand chelates in a meridional fashion. The chloride ligand in the axial position forms a long Cu-Cl distance of 2.4892 (9) Å. In contrast, the Cu-Cl distance from the equatorial chloride ligand is much shorter [2.2110 (7) Å]. Inter-molecular N-H⋯Cl and C-H⋯Cl hydrogen bonds link the complexes into a three-dimensional network.

No MeSH data available.


The structure of the title compound, showing 50% probability displacement ellipsoids for the non-hydrogen atoms. The H atoms are dipicted by circles of an arbitrary radius.
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Fap1: The structure of the title compound, showing 50% probability displacement ellipsoids for the non-hydrogen atoms. The H atoms are dipicted by circles of an arbitrary radius.


Dichlorido{N'-[1-(2-pyridin-2-yl)ethyl-idene]acetohydrazide-κN',O}copper(II).

Datta A, Das K, Jhou YM, Huang JH, Lee HM - Acta Crystallogr Sect E Struct Rep Online (2010)

The structure of the title compound, showing 50% probability displacement ellipsoids for the non-hydrogen atoms. The H atoms are dipicted by circles of an arbitrary radius.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3050222&req=5

Fap1: The structure of the title compound, showing 50% probability displacement ellipsoids for the non-hydrogen atoms. The H atoms are dipicted by circles of an arbitrary radius.
Bottom Line: The chloride ligand in the axial position forms a long Cu-Cl distance of 2.4892 (9) Å.In contrast, the Cu-Cl distance from the equatorial chloride ligand is much shorter [2.2110 (7) Å].Inter-molecular N-H⋯Cl and C-H⋯Cl hydrogen bonds link the complexes into a three-dimensional network.

View Article: PubMed Central - HTML - PubMed

Affiliation: National Changhua University of Education, Department of Chemistry, Changhua, Taiwan 50058.

ABSTRACT
In the title compound, [CuCl(2)(C(9)H(11)N(3)O)], the Cu(II) atom is in a distorted square-pyramidal CuCl(2)N(2)O coordination geometry. The tridentate acetohydrazide ligand chelates in a meridional fashion. The chloride ligand in the axial position forms a long Cu-Cl distance of 2.4892 (9) Å. In contrast, the Cu-Cl distance from the equatorial chloride ligand is much shorter [2.2110 (7) Å]. Inter-molecular N-H⋯Cl and C-H⋯Cl hydrogen bonds link the complexes into a three-dimensional network.

No MeSH data available.