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Poly[[μ(2)-(1Z,N'E)-2-(1,3-benzothia-zol-2-ylsulfan-yl)-N'-(2-oxidobenzyl-idene-κO:O)acetohydrazidato-κO,N'](pyridine-κN)copper(II)].

Bon VV, Orysyk SI, Pekhnyo VI - Acta Crystallogr Sect E Struct Rep Online (2010)

Bottom Line: The pyridine mol-ecule completes the square-planar base of the copper coordination environment.The crystal structure displays zigzag polymeric Cu-O-Cu chains along [001].Several weak π-π inter-actions between benzothia-zole rings were found in the same direction [centroid-centroid distances = 3.7484 (16), 3.7483 (16), 3.6731 (17) and 3.7649 (17) Å].

View Article: PubMed Central - HTML - PubMed

Affiliation: Institute of General and Inorganic Chemistry, NAS Ukraine, Kyiv, Prosp. Palladina 32/34, 03680, Ukraine.

ABSTRACT
In the title compound, [Cu(C(16)H(11)N(3)O(2)S(2))(C(5)H(5)N)](n), the Cu(II) atom displays a square-pyramidal CuN(2)O(3) coordination geometry with strong elongation in the vertex direction. The hydrazone mol-ecule is coordinated to the Cu(II) atom in a tridentate manner in the enolic form, creating five- and six-membered chelate metallarings. The pyridine mol-ecule completes the square-planar base of the copper coordination environment. The crystal structure displays zigzag polymeric Cu-O-Cu chains along [001]. Several weak π-π inter-actions between benzothia-zole rings were found in the same direction [centroid-centroid distances = 3.7484 (16), 3.7483 (16), 3.6731 (17) and 3.7649 (17) Å].

No MeSH data available.


Asymmetric unit of title compound with the atom numbering scheme. Displacement ellipsoids are shown at 50% probability level. H atoms are presented as a small spheres of arbitrary radius. Atoms O1i and Cu1ii generated using symmetry operators: (i) 3/2-x, y, -1/2+z; (ii) 3/2-x, y, 1/2+z.
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Fap1: Asymmetric unit of title compound with the atom numbering scheme. Displacement ellipsoids are shown at 50% probability level. H atoms are presented as a small spheres of arbitrary radius. Atoms O1i and Cu1ii generated using symmetry operators: (i) 3/2-x, y, -1/2+z; (ii) 3/2-x, y, 1/2+z.


Poly[[μ(2)-(1Z,N'E)-2-(1,3-benzothia-zol-2-ylsulfan-yl)-N'-(2-oxidobenzyl-idene-κO:O)acetohydrazidato-κO,N'](pyridine-κN)copper(II)].

Bon VV, Orysyk SI, Pekhnyo VI - Acta Crystallogr Sect E Struct Rep Online (2010)

Asymmetric unit of title compound with the atom numbering scheme. Displacement ellipsoids are shown at 50% probability level. H atoms are presented as a small spheres of arbitrary radius. Atoms O1i and Cu1ii generated using symmetry operators: (i) 3/2-x, y, -1/2+z; (ii) 3/2-x, y, 1/2+z.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3050211&req=5

Fap1: Asymmetric unit of title compound with the atom numbering scheme. Displacement ellipsoids are shown at 50% probability level. H atoms are presented as a small spheres of arbitrary radius. Atoms O1i and Cu1ii generated using symmetry operators: (i) 3/2-x, y, -1/2+z; (ii) 3/2-x, y, 1/2+z.
Bottom Line: The pyridine mol-ecule completes the square-planar base of the copper coordination environment.The crystal structure displays zigzag polymeric Cu-O-Cu chains along [001].Several weak π-π inter-actions between benzothia-zole rings were found in the same direction [centroid-centroid distances = 3.7484 (16), 3.7483 (16), 3.6731 (17) and 3.7649 (17) Å].

View Article: PubMed Central - HTML - PubMed

Affiliation: Institute of General and Inorganic Chemistry, NAS Ukraine, Kyiv, Prosp. Palladina 32/34, 03680, Ukraine.

ABSTRACT
In the title compound, [Cu(C(16)H(11)N(3)O(2)S(2))(C(5)H(5)N)](n), the Cu(II) atom displays a square-pyramidal CuN(2)O(3) coordination geometry with strong elongation in the vertex direction. The hydrazone mol-ecule is coordinated to the Cu(II) atom in a tridentate manner in the enolic form, creating five- and six-membered chelate metallarings. The pyridine mol-ecule completes the square-planar base of the copper coordination environment. The crystal structure displays zigzag polymeric Cu-O-Cu chains along [001]. Several weak π-π inter-actions between benzothia-zole rings were found in the same direction [centroid-centroid distances = 3.7484 (16), 3.7483 (16), 3.6731 (17) and 3.7649 (17) Å].

No MeSH data available.