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Bis(2,3,5,6-tetra-2-pyridyl-pyrazine-κN,N,N)nickel(II) dithio-cyanate dihydrate.

De la Pinta N, Fidalgo ML, Ezpeleta JM, Cortés R, Madariaga G - Acta Crystallogr Sect E Struct Rep Online (2010)

Bottom Line: In the title compound, [Ni(C(24)H(16)N(6))(2)](NCS)(2)·2H(2)O, the central Ni(II) ion is octahedrally coordinated by six N atoms of two tridentate 2,3,5,6-tetra-2-pyridyl-pyrazine ligands (tppz).Two thio-cyanate anions act as counter-ions and two water mol-ecules act as solvation agents.O-H⋯N hydrogen bonds are observed in the crystral structure.

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ABSTRACT
In the title compound, [Ni(C(24)H(16)N(6))(2)](NCS)(2)·2H(2)O, the central Ni(II) ion is octahedrally coordinated by six N atoms of two tridentate 2,3,5,6-tetra-2-pyridyl-pyrazine ligands (tppz). Two thio-cyanate anions act as counter-ions and two water mol-ecules act as solvation agents. O-H⋯N hydrogen bonds are observed in the crystral structure.

No MeSH data available.


Asymmetric unit of [Ni(C24H16N6)2](NCS)2.2H2O showing the most relevant labels. H atoms excluded for clarity. Ellipsoids drawn at 50% probability level.
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Fap1: Asymmetric unit of [Ni(C24H16N6)2](NCS)2.2H2O showing the most relevant labels. H atoms excluded for clarity. Ellipsoids drawn at 50% probability level.


Bis(2,3,5,6-tetra-2-pyridyl-pyrazine-κN,N,N)nickel(II) dithio-cyanate dihydrate.

De la Pinta N, Fidalgo ML, Ezpeleta JM, Cortés R, Madariaga G - Acta Crystallogr Sect E Struct Rep Online (2010)

Asymmetric unit of [Ni(C24H16N6)2](NCS)2.2H2O showing the most relevant labels. H atoms excluded for clarity. Ellipsoids drawn at 50% probability level.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3050193&req=5

Fap1: Asymmetric unit of [Ni(C24H16N6)2](NCS)2.2H2O showing the most relevant labels. H atoms excluded for clarity. Ellipsoids drawn at 50% probability level.
Bottom Line: In the title compound, [Ni(C(24)H(16)N(6))(2)](NCS)(2)·2H(2)O, the central Ni(II) ion is octahedrally coordinated by six N atoms of two tridentate 2,3,5,6-tetra-2-pyridyl-pyrazine ligands (tppz).Two thio-cyanate anions act as counter-ions and two water mol-ecules act as solvation agents.O-H⋯N hydrogen bonds are observed in the crystral structure.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the title compound, [Ni(C(24)H(16)N(6))(2)](NCS)(2)·2H(2)O, the central Ni(II) ion is octahedrally coordinated by six N atoms of two tridentate 2,3,5,6-tetra-2-pyridyl-pyrazine ligands (tppz). Two thio-cyanate anions act as counter-ions and two water mol-ecules act as solvation agents. O-H⋯N hydrogen bonds are observed in the crystral structure.

No MeSH data available.