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{1,1'-[Butane-1,4-diylbis(nitrilo-methyl-idyne)]di-2-naphtho-lato}copper(II) ethanol monosolvate.

Kargar H, Kia R - Acta Crystallogr Sect E Struct Rep Online (2010)

Bottom Line: The Cu(II) atom shows a distorted square-planar geometry.The dihedral angle between the two aromatic rings is 48.16 (13)°.The crystal structure is stabilized by inter-molecular O-H⋯O and C-H⋯O hydrogen bonds and inter-molecular π-π inter-actions with centroid-centroid distances in the range 3.485 (2)-3.845 (3) Å.

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ABSTRACT
The asymmetric unit of the title compound, [Cu(C(26)H(22)N(2)O(2))]·C(2)H(5)OH, comprises a Schiff base complex and an ethanol mol-ecule of crystallization. The Cu(II) atom shows a distorted square-planar geometry. The dihedral angle between the two aromatic rings is 48.16 (13)°. The crystal structure is stabilized by inter-molecular O-H⋯O and C-H⋯O hydrogen bonds and inter-molecular π-π inter-actions with centroid-centroid distances in the range 3.485 (2)-3.845 (3) Å.

No MeSH data available.


The packing of the title compound viewed down the a-axis showing dimer formation through the intermolecular C—H···O hydrogen bonds. All H atoms were removed for clarity except those involved in the hydrogen bonding. The intermolecular interactions are shown as dashed lines.
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Fap2: The packing of the title compound viewed down the a-axis showing dimer formation through the intermolecular C—H···O hydrogen bonds. All H atoms were removed for clarity except those involved in the hydrogen bonding. The intermolecular interactions are shown as dashed lines.


{1,1'-[Butane-1,4-diylbis(nitrilo-methyl-idyne)]di-2-naphtho-lato}copper(II) ethanol monosolvate.

Kargar H, Kia R - Acta Crystallogr Sect E Struct Rep Online (2010)

The packing of the title compound viewed down the a-axis showing dimer formation through the intermolecular C—H···O hydrogen bonds. All H atoms were removed for clarity except those involved in the hydrogen bonding. The intermolecular interactions are shown as dashed lines.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3050176&req=5

Fap2: The packing of the title compound viewed down the a-axis showing dimer formation through the intermolecular C—H···O hydrogen bonds. All H atoms were removed for clarity except those involved in the hydrogen bonding. The intermolecular interactions are shown as dashed lines.
Bottom Line: The Cu(II) atom shows a distorted square-planar geometry.The dihedral angle between the two aromatic rings is 48.16 (13)°.The crystal structure is stabilized by inter-molecular O-H⋯O and C-H⋯O hydrogen bonds and inter-molecular π-π inter-actions with centroid-centroid distances in the range 3.485 (2)-3.845 (3) Å.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
The asymmetric unit of the title compound, [Cu(C(26)H(22)N(2)O(2))]·C(2)H(5)OH, comprises a Schiff base complex and an ethanol mol-ecule of crystallization. The Cu(II) atom shows a distorted square-planar geometry. The dihedral angle between the two aromatic rings is 48.16 (13)°. The crystal structure is stabilized by inter-molecular O-H⋯O and C-H⋯O hydrogen bonds and inter-molecular π-π inter-actions with centroid-centroid distances in the range 3.485 (2)-3.845 (3) Å.

No MeSH data available.