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N-(2,4,6-Trimethyl-phen-yl)formamide.

Landman M, van der Westhuizen B, Bezuidenhout DI, Liles DC - Acta Crystallogr Sect E Struct Rep Online (2010)

Bottom Line: The title compound, C(10)H(13)NO, was obtained as the unexpected, almost exclusive, product in the attempted synthesis of a manganese(I)-N-heterocyclic carbene (NHC) complex.The dihedral angle between the planes of the formamide moiety and the aryl ring is 68.06 (10)°.In the crystal, mol-ecules are linked by N-H⋯O hydrogen bonds, forming infinite chains along the c axis.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, University of Pretoria, Private Bag X20, Hatfield 0028, South Africa.

ABSTRACT
The title compound, C(10)H(13)NO, was obtained as the unexpected, almost exclusive, product in the attempted synthesis of a manganese(I)-N-heterocyclic carbene (NHC) complex. The dihedral angle between the planes of the formamide moiety and the aryl ring is 68.06 (10)°. In the crystal, mol-ecules are linked by N-H⋯O hydrogen bonds, forming infinite chains along the c axis.

No MeSH data available.


The molecular structure of 1 showing the atomic numbering scheme. Displacement ellipsoids are shown at the 50% probability level and H atoms are shown as small spheres of arbitrary radii.
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Fap1: The molecular structure of 1 showing the atomic numbering scheme. Displacement ellipsoids are shown at the 50% probability level and H atoms are shown as small spheres of arbitrary radii.


N-(2,4,6-Trimethyl-phen-yl)formamide.

Landman M, van der Westhuizen B, Bezuidenhout DI, Liles DC - Acta Crystallogr Sect E Struct Rep Online (2010)

The molecular structure of 1 showing the atomic numbering scheme. Displacement ellipsoids are shown at the 50% probability level and H atoms are shown as small spheres of arbitrary radii.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3050174&req=5

Fap1: The molecular structure of 1 showing the atomic numbering scheme. Displacement ellipsoids are shown at the 50% probability level and H atoms are shown as small spheres of arbitrary radii.
Bottom Line: The title compound, C(10)H(13)NO, was obtained as the unexpected, almost exclusive, product in the attempted synthesis of a manganese(I)-N-heterocyclic carbene (NHC) complex.The dihedral angle between the planes of the formamide moiety and the aryl ring is 68.06 (10)°.In the crystal, mol-ecules are linked by N-H⋯O hydrogen bonds, forming infinite chains along the c axis.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, University of Pretoria, Private Bag X20, Hatfield 0028, South Africa.

ABSTRACT
The title compound, C(10)H(13)NO, was obtained as the unexpected, almost exclusive, product in the attempted synthesis of a manganese(I)-N-heterocyclic carbene (NHC) complex. The dihedral angle between the planes of the formamide moiety and the aryl ring is 68.06 (10)°. In the crystal, mol-ecules are linked by N-H⋯O hydrogen bonds, forming infinite chains along the c axis.

No MeSH data available.