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Aqua-bis-(benzoato-κO)(1,10-phenanthroline-κN,N')zinc(II).

Liu JZ, Zhang Z, Shi ZW, Gao P - Acta Crystallogr Sect E Struct Rep Online (2010)

Bottom Line: The Zn atom in the title compound, [Zn(C(7)H(5)O(2))(2)(C(12)H(8)N(2))(H(2)O)], is five-coordinate in a distorted trigonal-bipyramidal coordination environment involving two O atoms of two monodentate benzoates, two N atoms of a 1,10-phenanthroline mol-ecule and one O atom of a water mol-ecule.The axial positions are occupied by a carboxyl-ate O atom from the benzoate ligand and an N atom from the 1,10-phenanthroline ligand [N-Zn-O = 146.90 (7)°].The water mol-ecule forms an intra-molecular O-H⋯O hydrogen bond; an inter-molecular O-H⋯O hydrogen bond gives rise to a dimer.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, Guangxi University for Nationalities, Nanning 530006, People's Republic of China.

ABSTRACT
The Zn atom in the title compound, [Zn(C(7)H(5)O(2))(2)(C(12)H(8)N(2))(H(2)O)], is five-coordinate in a distorted trigonal-bipyramidal coordination environment involving two O atoms of two monodentate benzoates, two N atoms of a 1,10-phenanthroline mol-ecule and one O atom of a water mol-ecule. The axial positions are occupied by a carboxyl-ate O atom from the benzoate ligand and an N atom from the 1,10-phenanthroline ligand [N-Zn-O = 146.90 (7)°]. The water mol-ecule forms an intra-molecular O-H⋯O hydrogen bond; an inter-molecular O-H⋯O hydrogen bond gives rise to a dimer.

No MeSH data available.


Part of the packing of the title compand, viewed down the direction. Dashing lines indicate hydrongen bonds.
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Fap2: Part of the packing of the title compand, viewed down the direction. Dashing lines indicate hydrongen bonds.


Aqua-bis-(benzoato-κO)(1,10-phenanthroline-κN,N')zinc(II).

Liu JZ, Zhang Z, Shi ZW, Gao P - Acta Crystallogr Sect E Struct Rep Online (2010)

Part of the packing of the title compand, viewed down the direction. Dashing lines indicate hydrongen bonds.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3050171&req=5

Fap2: Part of the packing of the title compand, viewed down the direction. Dashing lines indicate hydrongen bonds.
Bottom Line: The Zn atom in the title compound, [Zn(C(7)H(5)O(2))(2)(C(12)H(8)N(2))(H(2)O)], is five-coordinate in a distorted trigonal-bipyramidal coordination environment involving two O atoms of two monodentate benzoates, two N atoms of a 1,10-phenanthroline mol-ecule and one O atom of a water mol-ecule.The axial positions are occupied by a carboxyl-ate O atom from the benzoate ligand and an N atom from the 1,10-phenanthroline ligand [N-Zn-O = 146.90 (7)°].The water mol-ecule forms an intra-molecular O-H⋯O hydrogen bond; an inter-molecular O-H⋯O hydrogen bond gives rise to a dimer.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, Guangxi University for Nationalities, Nanning 530006, People's Republic of China.

ABSTRACT
The Zn atom in the title compound, [Zn(C(7)H(5)O(2))(2)(C(12)H(8)N(2))(H(2)O)], is five-coordinate in a distorted trigonal-bipyramidal coordination environment involving two O atoms of two monodentate benzoates, two N atoms of a 1,10-phenanthroline mol-ecule and one O atom of a water mol-ecule. The axial positions are occupied by a carboxyl-ate O atom from the benzoate ligand and an N atom from the 1,10-phenanthroline ligand [N-Zn-O = 146.90 (7)°]. The water mol-ecule forms an intra-molecular O-H⋯O hydrogen bond; an inter-molecular O-H⋯O hydrogen bond gives rise to a dimer.

No MeSH data available.