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Bis(μ-2-phenyl-quinoline-4-carboxyl-ato)-κO,O':O;κO:O,O'-bis-[(2,2'-bipyridine-κN,N')(2-phenyl-quinoline-4-carboxyl-ato-κO,O')cadmium(II)].

Zha MQ, Li X, Bing Y - Acta Crystallogr Sect E Struct Rep Online (2010)

Bottom Line: The neutral binuclear title complex, [Cd(2)(C(16)H(10)NO(2))(4)(C(10)H(8)N(2))(2)], is centrosymmetric, with the inversion center generating the central (μ-O)(2)Cd(2) bridge.The Cd(II) ion is in a strongly distorted CdN(2)O(5) penta-gonal-bipyramidal geometry, defined by two N atoms from one 2,2'-bipyridine ligand and five O atoms from three 2-phenyl-quinoline-4-carboxyl-ate ligands, one monodentate, two bidentate.Weak inter-molecular π-π inter-actions [centroid-centroid distance = 3.712 (3) Å] help to establish the packing of the structure.

View Article: PubMed Central - HTML - PubMed

Affiliation: Faculty of Materials Science and Chemical Engineering, Ningbo University, Ningbo, Zhejiang 315211, People's Republic of China.

ABSTRACT
The neutral binuclear title complex, [Cd(2)(C(16)H(10)NO(2))(4)(C(10)H(8)N(2))(2)], is centrosymmetric, with the inversion center generating the central (μ-O)(2)Cd(2) bridge. The Cd(II) ion is in a strongly distorted CdN(2)O(5) penta-gonal-bipyramidal geometry, defined by two N atoms from one 2,2'-bipyridine ligand and five O atoms from three 2-phenyl-quinoline-4-carboxyl-ate ligands, one monodentate, two bidentate. Weak inter-molecular π-π inter-actions [centroid-centroid distance = 3.712 (3) Å] help to establish the packing of the structure.

No MeSH data available.


Related in: MedlinePlus

One-dimensional structure of the title complex..
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Fap2: One-dimensional structure of the title complex..


Bis(μ-2-phenyl-quinoline-4-carboxyl-ato)-κO,O':O;κO:O,O'-bis-[(2,2'-bipyridine-κN,N')(2-phenyl-quinoline-4-carboxyl-ato-κO,O')cadmium(II)].

Zha MQ, Li X, Bing Y - Acta Crystallogr Sect E Struct Rep Online (2010)

One-dimensional structure of the title complex..
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3050170&req=5

Fap2: One-dimensional structure of the title complex..
Bottom Line: The neutral binuclear title complex, [Cd(2)(C(16)H(10)NO(2))(4)(C(10)H(8)N(2))(2)], is centrosymmetric, with the inversion center generating the central (μ-O)(2)Cd(2) bridge.The Cd(II) ion is in a strongly distorted CdN(2)O(5) penta-gonal-bipyramidal geometry, defined by two N atoms from one 2,2'-bipyridine ligand and five O atoms from three 2-phenyl-quinoline-4-carboxyl-ate ligands, one monodentate, two bidentate.Weak inter-molecular π-π inter-actions [centroid-centroid distance = 3.712 (3) Å] help to establish the packing of the structure.

View Article: PubMed Central - HTML - PubMed

Affiliation: Faculty of Materials Science and Chemical Engineering, Ningbo University, Ningbo, Zhejiang 315211, People's Republic of China.

ABSTRACT
The neutral binuclear title complex, [Cd(2)(C(16)H(10)NO(2))(4)(C(10)H(8)N(2))(2)], is centrosymmetric, with the inversion center generating the central (μ-O)(2)Cd(2) bridge. The Cd(II) ion is in a strongly distorted CdN(2)O(5) penta-gonal-bipyramidal geometry, defined by two N atoms from one 2,2'-bipyridine ligand and five O atoms from three 2-phenyl-quinoline-4-carboxyl-ate ligands, one monodentate, two bidentate. Weak inter-molecular π-π inter-actions [centroid-centroid distance = 3.712 (3) Å] help to establish the packing of the structure.

No MeSH data available.


Related in: MedlinePlus