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Bis(μ-4-amino-3,5-dimethyl-4H-1,2,4-triazole)bis-[diiodidozinc(II)].

Zhang R, Chen Q, Yang X, Wu X - Acta Crystallogr Sect E Struct Rep Online (2010)

Bottom Line: In the title compound, [Zn(2)I(4)(C(4)H(8)N(4))(2)], the Zn(II) atom is coordinated in a distorted tetra-hedral geometry by two N atoms from the triazole rings of two 4-amino-3,5-dimethyl-4H-1,2,4-triazole (admt) ligands and two iodide ligands.Doubly bridging admt ligands connect two Zn(II) atoms, forming a centrosymmetric dimer.Weak N-H⋯I and C-H⋯I hydrogen bonds play an important role in the inter-molecular packing.

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ABSTRACT
In the title compound, [Zn(2)I(4)(C(4)H(8)N(4))(2)], the Zn(II) atom is coordinated in a distorted tetra-hedral geometry by two N atoms from the triazole rings of two 4-amino-3,5-dimethyl-4H-1,2,4-triazole (admt) ligands and two iodide ligands. Doubly bridging admt ligands connect two Zn(II) atoms, forming a centrosymmetric dimer. Weak N-H⋯I and C-H⋯I hydrogen bonds play an important role in the inter-molecular packing.

No MeSH data available.


The dimeric structure of the title compound, showing the atom-numbering scheme. Displacement ellipsoids are drawn at the 30% probability level. [Symmetry codes: (i) -x + 1, -y + 1, -z.]
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Fap1: The dimeric structure of the title compound, showing the atom-numbering scheme. Displacement ellipsoids are drawn at the 30% probability level. [Symmetry codes: (i) -x + 1, -y + 1, -z.]


Bis(μ-4-amino-3,5-dimethyl-4H-1,2,4-triazole)bis-[diiodidozinc(II)].

Zhang R, Chen Q, Yang X, Wu X - Acta Crystallogr Sect E Struct Rep Online (2010)

The dimeric structure of the title compound, showing the atom-numbering scheme. Displacement ellipsoids are drawn at the 30% probability level. [Symmetry codes: (i) -x + 1, -y + 1, -z.]
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3050150&req=5

Fap1: The dimeric structure of the title compound, showing the atom-numbering scheme. Displacement ellipsoids are drawn at the 30% probability level. [Symmetry codes: (i) -x + 1, -y + 1, -z.]
Bottom Line: In the title compound, [Zn(2)I(4)(C(4)H(8)N(4))(2)], the Zn(II) atom is coordinated in a distorted tetra-hedral geometry by two N atoms from the triazole rings of two 4-amino-3,5-dimethyl-4H-1,2,4-triazole (admt) ligands and two iodide ligands.Doubly bridging admt ligands connect two Zn(II) atoms, forming a centrosymmetric dimer.Weak N-H⋯I and C-H⋯I hydrogen bonds play an important role in the inter-molecular packing.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the title compound, [Zn(2)I(4)(C(4)H(8)N(4))(2)], the Zn(II) atom is coordinated in a distorted tetra-hedral geometry by two N atoms from the triazole rings of two 4-amino-3,5-dimethyl-4H-1,2,4-triazole (admt) ligands and two iodide ligands. Doubly bridging admt ligands connect two Zn(II) atoms, forming a centrosymmetric dimer. Weak N-H⋯I and C-H⋯I hydrogen bonds play an important role in the inter-molecular packing.

No MeSH data available.