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5-[(E)-2-Fluoro-benzyl-idene]-8-(2-fluoro-phen-yl)-2-hy-droxy-10-methyl-3,10-di-aza-hexa-cyclo-[10.7.1.1.0.0.0]henicosa-1(20),12,14,16,18-pentaen-6-one.

Kumar RS, Osman H, Yeap CS, Fun HK - Acta Crystallogr Sect E Struct Rep Online (2010)

Bottom Line: The two benzene rings make dihedral angles of 29.58 (5) and 76.33 (5)° with the mean plane of the 1,2-dihydro-acenaphthyl-ene unit.An intra-molecular O-H⋯N hydrogen bond helps to stabilize the mol-ecular structure.In the crystal, inter-molecular C-H⋯F hydrogen bonds link the mol-ecules into [010] chains.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the title compound, C(33)H(26)F(2)N(2)O(2), the piperidone ring adopts a half-chair conformation and the pyrrolidine rings adopt half-chair and envelope conformations. The two benzene rings make dihedral angles of 29.58 (5) and 76.33 (5)° with the mean plane of the 1,2-dihydro-acenaphthyl-ene unit. An intra-molecular O-H⋯N hydrogen bond helps to stabilize the mol-ecular structure. In the crystal, inter-molecular C-H⋯F hydrogen bonds link the mol-ecules into [010] chains. Weak C-H⋯π inter-actions are also observed.

No MeSH data available.


Related in: MedlinePlus

The molecular structure of the title compound with 50% probability ellipsoids for non-H atoms.
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Related In: Results  -  Collection

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Fap1: The molecular structure of the title compound with 50% probability ellipsoids for non-H atoms.


5-[(E)-2-Fluoro-benzyl-idene]-8-(2-fluoro-phen-yl)-2-hy-droxy-10-methyl-3,10-di-aza-hexa-cyclo-[10.7.1.1.0.0.0]henicosa-1(20),12,14,16,18-pentaen-6-one.

Kumar RS, Osman H, Yeap CS, Fun HK - Acta Crystallogr Sect E Struct Rep Online (2010)

The molecular structure of the title compound with 50% probability ellipsoids for non-H atoms.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3050149&req=5

Fap1: The molecular structure of the title compound with 50% probability ellipsoids for non-H atoms.
Bottom Line: The two benzene rings make dihedral angles of 29.58 (5) and 76.33 (5)° with the mean plane of the 1,2-dihydro-acenaphthyl-ene unit.An intra-molecular O-H⋯N hydrogen bond helps to stabilize the mol-ecular structure.In the crystal, inter-molecular C-H⋯F hydrogen bonds link the mol-ecules into [010] chains.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the title compound, C(33)H(26)F(2)N(2)O(2), the piperidone ring adopts a half-chair conformation and the pyrrolidine rings adopt half-chair and envelope conformations. The two benzene rings make dihedral angles of 29.58 (5) and 76.33 (5)° with the mean plane of the 1,2-dihydro-acenaphthyl-ene unit. An intra-molecular O-H⋯N hydrogen bond helps to stabilize the mol-ecular structure. In the crystal, inter-molecular C-H⋯F hydrogen bonds link the mol-ecules into [010] chains. Weak C-H⋯π inter-actions are also observed.

No MeSH data available.


Related in: MedlinePlus