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Poly[[bis-[μ-1,2-bis-(4-pyrid-yl)ethene]bis-(trichloro-acetato)-cadmium(II)] monohydrate].

Kim JH, Kim C, Kim Y - Acta Crystallogr Sect E Struct Rep Online (2010)

Bottom Line: Two trichloro-acetate ligands complete the coordination around the Cd(II )ion, forming a distorted octa-hedral environment.In the crystal, solvent water mol-ecules, which also lie on twofold rotation axes, form inter-molecular O-H⋯O hydrogen bonds, which connect the two-dimensional structure into a three-dimensional network.The crystal studied was an inversion twin, the refined ratio of twin components being 0.75 (4):0.25 (4).

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ABSTRACT
In the crystal structure of the title compound, {[Cd(C(2)Cl(3)O(2))(2)(C(12)H(10)N(2))(2)]·H(2)O}(n), the Cd(II) ion lies on a twofold rotation axis and 1,2-bis-(4-pyrid-yl)ethene ligands bridge symmetry-related Cd(II) ions, forming a two-dimensional structure. Two trichloro-acetate ligands complete the coordination around the Cd(II )ion, forming a distorted octa-hedral environment. In the crystal, solvent water mol-ecules, which also lie on twofold rotation axes, form inter-molecular O-H⋯O hydrogen bonds, which connect the two-dimensional structure into a three-dimensional network. The crystal studied was an inversion twin, the refined ratio of twin components being 0.75 (4):0.25 (4).

No MeSH data available.


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Part of a two-dimensional sheet of the title compound.
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Fap2: Part of a two-dimensional sheet of the title compound.


Poly[[bis-[μ-1,2-bis-(4-pyrid-yl)ethene]bis-(trichloro-acetato)-cadmium(II)] monohydrate].

Kim JH, Kim C, Kim Y - Acta Crystallogr Sect E Struct Rep Online (2010)

Part of a two-dimensional sheet of the title compound.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3050134&req=5

Fap2: Part of a two-dimensional sheet of the title compound.
Bottom Line: Two trichloro-acetate ligands complete the coordination around the Cd(II )ion, forming a distorted octa-hedral environment.In the crystal, solvent water mol-ecules, which also lie on twofold rotation axes, form inter-molecular O-H⋯O hydrogen bonds, which connect the two-dimensional structure into a three-dimensional network.The crystal studied was an inversion twin, the refined ratio of twin components being 0.75 (4):0.25 (4).

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the crystal structure of the title compound, {[Cd(C(2)Cl(3)O(2))(2)(C(12)H(10)N(2))(2)]·H(2)O}(n), the Cd(II) ion lies on a twofold rotation axis and 1,2-bis-(4-pyrid-yl)ethene ligands bridge symmetry-related Cd(II) ions, forming a two-dimensional structure. Two trichloro-acetate ligands complete the coordination around the Cd(II )ion, forming a distorted octa-hedral environment. In the crystal, solvent water mol-ecules, which also lie on twofold rotation axes, form inter-molecular O-H⋯O hydrogen bonds, which connect the two-dimensional structure into a three-dimensional network. The crystal studied was an inversion twin, the refined ratio of twin components being 0.75 (4):0.25 (4).

No MeSH data available.


Related in: MedlinePlus