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cis-(Pyridin-2-ylcarbonimidodithio-ato-κS,S')bis-(triphenyl-phosphane-κP)palladium(II).

Bon VV, Orysyk SI, Pekhnyo VI - Acta Crystallogr Sect E Struct Rep Online (2010)

Bottom Line: The title compound, [Pd(C(6)H(4)N(2)S(2))(C(18)H(15)P)(2)], was obtained as a minor product from the reaction of trans-PdCl(2)(PPh(3))(2) with piperazine-1,4-dicarbothioic acid bis-(pyridin-2-yl)amide.The Pd(II) atom displays a slightly distorted square-planar PdP(2)S(2) geometry with a bidentately coordinated pyridin-2-ylcarbonimidodithio-ate ligand and two triphenyl-phosphine mol-ecules, coordinated in cis positions.The crystal structure features weak π-π [centroid-centroid distance =3.7327(15) Å] and C-H⋯π inter-actions and contains an almost spherically shaped void of 50.4 Å(3) per unit cell.

View Article: PubMed Central - HTML - PubMed

Affiliation: Institute of General and Inorganic Chemistry, NAS Ukraine, Kyiv, prosp. Palladina 32/34, 03680, Ukraine.

ABSTRACT
The title compound, [Pd(C(6)H(4)N(2)S(2))(C(18)H(15)P)(2)], was obtained as a minor product from the reaction of trans-PdCl(2)(PPh(3))(2) with piperazine-1,4-dicarbothioic acid bis-(pyridin-2-yl)amide. The Pd(II) atom displays a slightly distorted square-planar PdP(2)S(2) geometry with a bidentately coordinated pyridin-2-ylcarbonimidodithio-ate ligand and two triphenyl-phosphine mol-ecules, coordinated in cis positions. The crystal structure features weak π-π [centroid-centroid distance =3.7327(15) Å] and C-H⋯π inter-actions and contains an almost spherically shaped void of 50.4 Å(3) per unit cell.

No MeSH data available.


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Packing diagram of title compound. Dark spheres indicate voids.
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Fap2: Packing diagram of title compound. Dark spheres indicate voids.


cis-(Pyridin-2-ylcarbonimidodithio-ato-κS,S')bis-(triphenyl-phosphane-κP)palladium(II).

Bon VV, Orysyk SI, Pekhnyo VI - Acta Crystallogr Sect E Struct Rep Online (2010)

Packing diagram of title compound. Dark spheres indicate voids.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3050130&req=5

Fap2: Packing diagram of title compound. Dark spheres indicate voids.
Bottom Line: The title compound, [Pd(C(6)H(4)N(2)S(2))(C(18)H(15)P)(2)], was obtained as a minor product from the reaction of trans-PdCl(2)(PPh(3))(2) with piperazine-1,4-dicarbothioic acid bis-(pyridin-2-yl)amide.The Pd(II) atom displays a slightly distorted square-planar PdP(2)S(2) geometry with a bidentately coordinated pyridin-2-ylcarbonimidodithio-ate ligand and two triphenyl-phosphine mol-ecules, coordinated in cis positions.The crystal structure features weak π-π [centroid-centroid distance =3.7327(15) Å] and C-H⋯π inter-actions and contains an almost spherically shaped void of 50.4 Å(3) per unit cell.

View Article: PubMed Central - HTML - PubMed

Affiliation: Institute of General and Inorganic Chemistry, NAS Ukraine, Kyiv, prosp. Palladina 32/34, 03680, Ukraine.

ABSTRACT
The title compound, [Pd(C(6)H(4)N(2)S(2))(C(18)H(15)P)(2)], was obtained as a minor product from the reaction of trans-PdCl(2)(PPh(3))(2) with piperazine-1,4-dicarbothioic acid bis-(pyridin-2-yl)amide. The Pd(II) atom displays a slightly distorted square-planar PdP(2)S(2) geometry with a bidentately coordinated pyridin-2-ylcarbonimidodithio-ate ligand and two triphenyl-phosphine mol-ecules, coordinated in cis positions. The crystal structure features weak π-π [centroid-centroid distance =3.7327(15) Å] and C-H⋯π inter-actions and contains an almost spherically shaped void of 50.4 Å(3) per unit cell.

No MeSH data available.


Related in: MedlinePlus