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(2,7-Dimeth-oxy-naphthalen-1-yl)(3-nitro-phen-yl)methanone.

Kataoka K, Nishijima T, Nagasawa A, Okamoto A, Yonezawa N - Acta Crystallogr Sect E Struct Rep Online (2010)

Bottom Line: The inter-planar angle between the naphthalene ring system and the benzene ring is 69.59 (5)°.The dihedral angle between the bridging carbonyl C-C(=O)-C plane and the naphthalene ring system is 61.02 (6)°, which is far larger than that between the bridging carbonyl plane and the benzene ring [12.68 (7)°].In the crystal, the packing is mainly stabilized by C-H⋯O inter-actions between an H atom of the benzene ring and an O atom of the nitro group.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Organic and Polymer Materials Chemistry, Tokyo University of Agriculture & Technology, 2-24-16 Naka-machi, Koganei, Tokyo 184-8588, Japan.

ABSTRACT
The title compound, C(19)H(15)NO(5), has an intra-molecular C-H⋯O=C hydrogen bond between a naphthalene H atom and the O atom of the carbonyl group. The inter-planar angle between the naphthalene ring system and the benzene ring is 69.59 (5)°. The dihedral angle between the bridging carbonyl C-C(=O)-C plane and the naphthalene ring system is 61.02 (6)°, which is far larger than that between the bridging carbonyl plane and the benzene ring [12.68 (7)°]. The nitro group is slightly out of the plane of the benzene ring [O-N-C-C torsion angle = 4.97 (17)°]. In the crystal, the packing is mainly stabilized by C-H⋯O inter-actions between an H atom of the benzene ring and an O atom of the nitro group.

No MeSH data available.


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The asymmetric unit of compound (I), showing 50% probability displacement ellipsoids. The dashed line indicates an intramolecular C—H···O hydrogen bond.
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Fap1: The asymmetric unit of compound (I), showing 50% probability displacement ellipsoids. The dashed line indicates an intramolecular C—H···O hydrogen bond.


(2,7-Dimeth-oxy-naphthalen-1-yl)(3-nitro-phen-yl)methanone.

Kataoka K, Nishijima T, Nagasawa A, Okamoto A, Yonezawa N - Acta Crystallogr Sect E Struct Rep Online (2010)

The asymmetric unit of compound (I), showing 50% probability displacement ellipsoids. The dashed line indicates an intramolecular C—H···O hydrogen bond.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3009278&req=5

Fap1: The asymmetric unit of compound (I), showing 50% probability displacement ellipsoids. The dashed line indicates an intramolecular C—H···O hydrogen bond.
Bottom Line: The inter-planar angle between the naphthalene ring system and the benzene ring is 69.59 (5)°.The dihedral angle between the bridging carbonyl C-C(=O)-C plane and the naphthalene ring system is 61.02 (6)°, which is far larger than that between the bridging carbonyl plane and the benzene ring [12.68 (7)°].In the crystal, the packing is mainly stabilized by C-H⋯O inter-actions between an H atom of the benzene ring and an O atom of the nitro group.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Organic and Polymer Materials Chemistry, Tokyo University of Agriculture & Technology, 2-24-16 Naka-machi, Koganei, Tokyo 184-8588, Japan.

ABSTRACT
The title compound, C(19)H(15)NO(5), has an intra-molecular C-H⋯O=C hydrogen bond between a naphthalene H atom and the O atom of the carbonyl group. The inter-planar angle between the naphthalene ring system and the benzene ring is 69.59 (5)°. The dihedral angle between the bridging carbonyl C-C(=O)-C plane and the naphthalene ring system is 61.02 (6)°, which is far larger than that between the bridging carbonyl plane and the benzene ring [12.68 (7)°]. The nitro group is slightly out of the plane of the benzene ring [O-N-C-C torsion angle = 4.97 (17)°]. In the crystal, the packing is mainly stabilized by C-H⋯O inter-actions between an H atom of the benzene ring and an O atom of the nitro group.

No MeSH data available.


Related in: MedlinePlus