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9-Phenyl-10H-acridinium trifluoro-methane-sulfonate.

Trzybiński D, Zadykowicz B, Krzymiński K, Sikorski A, Błażejowski J - Acta Crystallogr Sect E Struct Rep Online (2010)

Bottom Line: The acridine ring system and the phenyl ring are oriented at an angle of 80.1 (1)° with respect to each other.The mean planes of adjacent acridine units are either parallel or inclined at an angle of 35.6 (1)°.The trifluoro-methane-sulfonate anions are disordered over two positions; the site occupancy factors are 0.591 (8) and 0.409 (8).

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Affiliation: Faculty of Chemistry, University of Gdańsk, J. Sobieskiego 18, 80-952 Gdańsk, Poland.

ABSTRACT
In the crystal structure of the title compound, C(19)H(14)N(+)·CF(3)SO(3) (-), the cations are linked to each other by very weak C-H⋯π inter-actions, while the cations and anions are connected by N-H⋯O, C-H⋯O and S-O⋯π inter-actions. The acridine ring system and the phenyl ring are oriented at an angle of 80.1 (1)° with respect to each other. The mean planes of adjacent acridine units are either parallel or inclined at an angle of 35.6 (1)°. The trifluoro-methane-sulfonate anions are disordered over two positions; the site occupancy factors are 0.591 (8) and 0.409 (8).

No MeSH data available.


Related in: MedlinePlus

The molecular structure of the title compound showing the atom-labeling scheme. The N–H···O and C–H···O interactions are represented by dashed lines. Displacement ellipsoids are drawn at the 25% probability level and H atoms are shown as small spheres of arbitrary radius. Cg1, Cg2 and Cg3 denote the ring centroids.
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Fap1: The molecular structure of the title compound showing the atom-labeling scheme. The N–H···O and C–H···O interactions are represented by dashed lines. Displacement ellipsoids are drawn at the 25% probability level and H atoms are shown as small spheres of arbitrary radius. Cg1, Cg2 and Cg3 denote the ring centroids.


9-Phenyl-10H-acridinium trifluoro-methane-sulfonate.

Trzybiński D, Zadykowicz B, Krzymiński K, Sikorski A, Błażejowski J - Acta Crystallogr Sect E Struct Rep Online (2010)

The molecular structure of the title compound showing the atom-labeling scheme. The N–H···O and C–H···O interactions are represented by dashed lines. Displacement ellipsoids are drawn at the 25% probability level and H atoms are shown as small spheres of arbitrary radius. Cg1, Cg2 and Cg3 denote the ring centroids.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3009277&req=5

Fap1: The molecular structure of the title compound showing the atom-labeling scheme. The N–H···O and C–H···O interactions are represented by dashed lines. Displacement ellipsoids are drawn at the 25% probability level and H atoms are shown as small spheres of arbitrary radius. Cg1, Cg2 and Cg3 denote the ring centroids.
Bottom Line: The acridine ring system and the phenyl ring are oriented at an angle of 80.1 (1)° with respect to each other.The mean planes of adjacent acridine units are either parallel or inclined at an angle of 35.6 (1)°.The trifluoro-methane-sulfonate anions are disordered over two positions; the site occupancy factors are 0.591 (8) and 0.409 (8).

View Article: PubMed Central - HTML - PubMed

Affiliation: Faculty of Chemistry, University of Gdańsk, J. Sobieskiego 18, 80-952 Gdańsk, Poland.

ABSTRACT
In the crystal structure of the title compound, C(19)H(14)N(+)·CF(3)SO(3) (-), the cations are linked to each other by very weak C-H⋯π inter-actions, while the cations and anions are connected by N-H⋯O, C-H⋯O and S-O⋯π inter-actions. The acridine ring system and the phenyl ring are oriented at an angle of 80.1 (1)° with respect to each other. The mean planes of adjacent acridine units are either parallel or inclined at an angle of 35.6 (1)°. The trifluoro-methane-sulfonate anions are disordered over two positions; the site occupancy factors are 0.591 (8) and 0.409 (8).

No MeSH data available.


Related in: MedlinePlus