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Bis{μ-N-[(dimethyl-amino)-dimethyl-sil-yl]-2,6-dimethyl-anilido}-κN:N';κN':N-dicopper(I).

Chen J - Acta Crystallogr Sect E Struct Rep Online (2010)

Bottom Line: The two N atoms exhibit different affinities for the metal atom.The Cu-N(amino) bond is longer than the Cu-N(anilido) bond by 0.079 Å.The core of the mol-ecule, the [Cu-N-Si-N](2) eight-membered ring, adopts a chair configuration.

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Affiliation: Department of Chemistry, Taiyuan Teachers College, Taiyuan 030031, People's Republic of China.

ABSTRACT
The title compound, [Cu(2)(C(12)H(21)N(2)Si)(2)], is a binuclear Cu(I) complex. The dimeric mol-ecule has an inversion center located at the mid-point of the Cu-Cu bond [Cu-Cu = 2.7209 (7) Å]. The bidentate ligand behaves in an N:N'-bridging mode, coordinating the metal atoms. The N-Cu-N unit is close to being linear [176.60 (8)°]. The two N atoms exhibit different affinities for the metal atom. The Cu-N(amino) bond is longer than the Cu-N(anilido) bond by 0.079 Å. The core of the mol-ecule, the [Cu-N-Si-N](2) eight-membered ring, adopts a chair configuration.

No MeSH data available.


Related in: MedlinePlus

The molecular structure, showing the atom-numbering scheme. Displacement ellipsoids are drawn at the 30% probability level. Symmetry code used to generate second part: 1-x, 2-y, 2-z.
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Fap1: The molecular structure, showing the atom-numbering scheme. Displacement ellipsoids are drawn at the 30% probability level. Symmetry code used to generate second part: 1-x, 2-y, 2-z.


Bis{μ-N-[(dimethyl-amino)-dimethyl-sil-yl]-2,6-dimethyl-anilido}-κN:N';κN':N-dicopper(I).

Chen J - Acta Crystallogr Sect E Struct Rep Online (2010)

The molecular structure, showing the atom-numbering scheme. Displacement ellipsoids are drawn at the 30% probability level. Symmetry code used to generate second part: 1-x, 2-y, 2-z.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3009272&req=5

Fap1: The molecular structure, showing the atom-numbering scheme. Displacement ellipsoids are drawn at the 30% probability level. Symmetry code used to generate second part: 1-x, 2-y, 2-z.
Bottom Line: The two N atoms exhibit different affinities for the metal atom.The Cu-N(amino) bond is longer than the Cu-N(anilido) bond by 0.079 Å.The core of the mol-ecule, the [Cu-N-Si-N](2) eight-membered ring, adopts a chair configuration.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, Taiyuan Teachers College, Taiyuan 030031, People's Republic of China.

ABSTRACT
The title compound, [Cu(2)(C(12)H(21)N(2)Si)(2)], is a binuclear Cu(I) complex. The dimeric mol-ecule has an inversion center located at the mid-point of the Cu-Cu bond [Cu-Cu = 2.7209 (7) Å]. The bidentate ligand behaves in an N:N'-bridging mode, coordinating the metal atoms. The N-Cu-N unit is close to being linear [176.60 (8)°]. The two N atoms exhibit different affinities for the metal atom. The Cu-N(amino) bond is longer than the Cu-N(anilido) bond by 0.079 Å. The core of the mol-ecule, the [Cu-N-Si-N](2) eight-membered ring, adopts a chair configuration.

No MeSH data available.


Related in: MedlinePlus