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catena-Poly[[(1,10-phenanthroline-κN,N')cadmium(II)]-μ-oxalato-κO,O:O,O].

Lv YK, Gan LH, Cao YJ, Gao BF, Chen LH - Acta Crystallogr Sect E Struct Rep Online (2010)

Bottom Line: In the title complex, [Cd(C(2)O(4))(C(12)H(8)N(2))](n), the Cd(II) atom has a distorted octa-hedral coordination, defined by four O atoms from two symmetry-related oxalate ligands and by two N atoms from a bidentate 1,10-phenanthroline ligand.Each oxalate ligand bridges two Cd(II) atoms, generating a zigzag chain structure propagating along [100].The packing of the structure is consolidated by non-classical C-H⋯O hydrogen-bonding inter-actions.

View Article: PubMed Central - HTML - PubMed

Affiliation: Chemistry Department, Tongji University, Shanghai 200092, People's Republic of China.

ABSTRACT
In the title complex, [Cd(C(2)O(4))(C(12)H(8)N(2))](n), the Cd(II) atom has a distorted octa-hedral coordination, defined by four O atoms from two symmetry-related oxalate ligands and by two N atoms from a bidentate 1,10-phenanthroline ligand. Each oxalate ligand bridges two Cd(II) atoms, generating a zigzag chain structure propagating along [100]. The packing of the structure is consolidated by non-classical C-H⋯O hydrogen-bonding inter-actions.

No MeSH data available.


The asymmetric unit and some symmetry-related atoms of the title complex. Displacement ellipsoids are plotted at the 30% probability level and H atoms are not labeled. [Symmetry codes: (i) x-0.5, -y-0.5, z; (ii) x+0.5, -y-0.5, z.]
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Fap1: The asymmetric unit and some symmetry-related atoms of the title complex. Displacement ellipsoids are plotted at the 30% probability level and H atoms are not labeled. [Symmetry codes: (i) x-0.5, -y-0.5, z; (ii) x+0.5, -y-0.5, z.]


catena-Poly[[(1,10-phenanthroline-κN,N')cadmium(II)]-μ-oxalato-κO,O:O,O].

Lv YK, Gan LH, Cao YJ, Gao BF, Chen LH - Acta Crystallogr Sect E Struct Rep Online (2010)

The asymmetric unit and some symmetry-related atoms of the title complex. Displacement ellipsoids are plotted at the 30% probability level and H atoms are not labeled. [Symmetry codes: (i) x-0.5, -y-0.5, z; (ii) x+0.5, -y-0.5, z.]
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3009255&req=5

Fap1: The asymmetric unit and some symmetry-related atoms of the title complex. Displacement ellipsoids are plotted at the 30% probability level and H atoms are not labeled. [Symmetry codes: (i) x-0.5, -y-0.5, z; (ii) x+0.5, -y-0.5, z.]
Bottom Line: In the title complex, [Cd(C(2)O(4))(C(12)H(8)N(2))](n), the Cd(II) atom has a distorted octa-hedral coordination, defined by four O atoms from two symmetry-related oxalate ligands and by two N atoms from a bidentate 1,10-phenanthroline ligand.Each oxalate ligand bridges two Cd(II) atoms, generating a zigzag chain structure propagating along [100].The packing of the structure is consolidated by non-classical C-H⋯O hydrogen-bonding inter-actions.

View Article: PubMed Central - HTML - PubMed

Affiliation: Chemistry Department, Tongji University, Shanghai 200092, People's Republic of China.

ABSTRACT
In the title complex, [Cd(C(2)O(4))(C(12)H(8)N(2))](n), the Cd(II) atom has a distorted octa-hedral coordination, defined by four O atoms from two symmetry-related oxalate ligands and by two N atoms from a bidentate 1,10-phenanthroline ligand. Each oxalate ligand bridges two Cd(II) atoms, generating a zigzag chain structure propagating along [100]. The packing of the structure is consolidated by non-classical C-H⋯O hydrogen-bonding inter-actions.

No MeSH data available.