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Chlorido(η-cyclo-octa-1,5-diene)(N,N'-diethyl-thio-urea-κS)rhodium(I).

Brancatelli G, Drommi D, Bruno G, Faraone F - Acta Crystallogr Sect E Struct Rep Online (2010)

Bottom Line: If the midpoints of these two bonds are taken into account, the Rh atom exhibits a distorted square-planar coordination.The syn conformation of the N,N'-diethyl-thio-urea ligand with respect to the Cl atom is stabilized by an intra-molecular N-H⋯Cl hydrogen bond.A weak inter-molecular N-H⋯Cl inter-action links mol-ecules along the a axis.

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Affiliation: Dip. di Chimica Inorganica Chimica Analitica e Chimica Fisica, Universitá degli Studi di Messina, Via Salita Sperone 31, I-98166 Vill. S. Agata - Messina, Italy.

ABSTRACT
In the title rhodium(I) complex, [RhCl(C(8)H(12))(C(5)H(12)N(2)S)], N,N'-diethyl-thio-urea acts as a monodenate S-donor ligand. The rhodium(I) coordination sphere is completed by the Cl atom and the COD [= 1,5-cyclo-octa-diene] ligand inter-acting through the π-electrons of the double bonds. If the midpoints of these two bonds are taken into account, the Rh atom exhibits a distorted square-planar coordination. The syn conformation of the N,N'-diethyl-thio-urea ligand with respect to the Cl atom is stabilized by an intra-molecular N-H⋯Cl hydrogen bond. A weak inter-molecular N-H⋯Cl inter-action links mol-ecules along the a axis.

No MeSH data available.


ORTEP view of compound (I) showing atomic labeling scheme and displacement ellipsoids at 50% probability for non-H atoms.
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Fap1: ORTEP view of compound (I) showing atomic labeling scheme and displacement ellipsoids at 50% probability for non-H atoms.


Chlorido(η-cyclo-octa-1,5-diene)(N,N'-diethyl-thio-urea-κS)rhodium(I).

Brancatelli G, Drommi D, Bruno G, Faraone F - Acta Crystallogr Sect E Struct Rep Online (2010)

ORTEP view of compound (I) showing atomic labeling scheme and displacement ellipsoids at 50% probability for non-H atoms.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3009226&req=5

Fap1: ORTEP view of compound (I) showing atomic labeling scheme and displacement ellipsoids at 50% probability for non-H atoms.
Bottom Line: If the midpoints of these two bonds are taken into account, the Rh atom exhibits a distorted square-planar coordination.The syn conformation of the N,N'-diethyl-thio-urea ligand with respect to the Cl atom is stabilized by an intra-molecular N-H⋯Cl hydrogen bond.A weak inter-molecular N-H⋯Cl inter-action links mol-ecules along the a axis.

View Article: PubMed Central - HTML - PubMed

Affiliation: Dip. di Chimica Inorganica Chimica Analitica e Chimica Fisica, Universitá degli Studi di Messina, Via Salita Sperone 31, I-98166 Vill. S. Agata - Messina, Italy.

ABSTRACT
In the title rhodium(I) complex, [RhCl(C(8)H(12))(C(5)H(12)N(2)S)], N,N'-diethyl-thio-urea acts as a monodenate S-donor ligand. The rhodium(I) coordination sphere is completed by the Cl atom and the COD [= 1,5-cyclo-octa-diene] ligand inter-acting through the π-electrons of the double bonds. If the midpoints of these two bonds are taken into account, the Rh atom exhibits a distorted square-planar coordination. The syn conformation of the N,N'-diethyl-thio-urea ligand with respect to the Cl atom is stabilized by an intra-molecular N-H⋯Cl hydrogen bond. A weak inter-molecular N-H⋯Cl inter-action links mol-ecules along the a axis.

No MeSH data available.