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trans-Carbonyl-chloridobis[tris-(4-chloro-phen-yl)phosphane]rhodium(I) acetone monosolvate.

Burgoyne AR, Meijboom R, Muller A, Omondi BO - Acta Crystallogr Sect E Struct Rep Online (2010)

Bottom Line: The title compound, trans-[RhCl(C(18)H(12)Cl(3)P)(2)(CO)]·C(3)H(6)O, contains an Rh(I) atom in a distorted square-planar coordination with a P-Rh-P angle of 175.27 (2)° and Rh-P bond lengths of 2.3127 (4) and 2.3219 (4) Å.The rhodium complexes link each other through weak inter-molecular contacts between the acetone methyl groups and the carbonyl O atom.Inter-actions between the acetone solvent mol-ecule and the Cl-Rh unit results in a reduced P-Rh-Cl angle of 86.675 (15)°.

View Article: PubMed Central - HTML - PubMed

Affiliation: Research Centre for Synthesis and Catalysis, Department of Chemistry, University of Johannesburg, PO Box 524 Auckland Park, Johannesburg, 2006, South Africa.

ABSTRACT
The title compound, trans-[RhCl(C(18)H(12)Cl(3)P)(2)(CO)]·C(3)H(6)O, contains an Rh(I) atom in a distorted square-planar coordination with a P-Rh-P angle of 175.27 (2)° and Rh-P bond lengths of 2.3127 (4) and 2.3219 (4) Å. The rhodium complexes link each other through weak inter-molecular contacts between the acetone methyl groups and the carbonyl O atom. Inter-actions between the acetone solvent mol-ecule and the Cl-Rh unit results in a reduced P-Rh-Cl angle of 86.675 (15)°.

No MeSH data available.


View of (I) (50% probability displacement ellipsoids) with H atoms omitted for clarity. The carbon atoms have been numbered sequentially and some labels have been omitted for clarity.
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Fap1: View of (I) (50% probability displacement ellipsoids) with H atoms omitted for clarity. The carbon atoms have been numbered sequentially and some labels have been omitted for clarity.


trans-Carbonyl-chloridobis[tris-(4-chloro-phen-yl)phosphane]rhodium(I) acetone monosolvate.

Burgoyne AR, Meijboom R, Muller A, Omondi BO - Acta Crystallogr Sect E Struct Rep Online (2010)

View of (I) (50% probability displacement ellipsoids) with H atoms omitted for clarity. The carbon atoms have been numbered sequentially and some labels have been omitted for clarity.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3009219&req=5

Fap1: View of (I) (50% probability displacement ellipsoids) with H atoms omitted for clarity. The carbon atoms have been numbered sequentially and some labels have been omitted for clarity.
Bottom Line: The title compound, trans-[RhCl(C(18)H(12)Cl(3)P)(2)(CO)]·C(3)H(6)O, contains an Rh(I) atom in a distorted square-planar coordination with a P-Rh-P angle of 175.27 (2)° and Rh-P bond lengths of 2.3127 (4) and 2.3219 (4) Å.The rhodium complexes link each other through weak inter-molecular contacts between the acetone methyl groups and the carbonyl O atom.Inter-actions between the acetone solvent mol-ecule and the Cl-Rh unit results in a reduced P-Rh-Cl angle of 86.675 (15)°.

View Article: PubMed Central - HTML - PubMed

Affiliation: Research Centre for Synthesis and Catalysis, Department of Chemistry, University of Johannesburg, PO Box 524 Auckland Park, Johannesburg, 2006, South Africa.

ABSTRACT
The title compound, trans-[RhCl(C(18)H(12)Cl(3)P)(2)(CO)]·C(3)H(6)O, contains an Rh(I) atom in a distorted square-planar coordination with a P-Rh-P angle of 175.27 (2)° and Rh-P bond lengths of 2.3127 (4) and 2.3219 (4) Å. The rhodium complexes link each other through weak inter-molecular contacts between the acetone methyl groups and the carbonyl O atom. Inter-actions between the acetone solvent mol-ecule and the Cl-Rh unit results in a reduced P-Rh-Cl angle of 86.675 (15)°.

No MeSH data available.