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(2-Carb-oxy-acetato-κO,O)(rac-5,5,7,12,12,14-hexa-methyl-1,4,8,11-tetra-aza-cyclo-tetra-decane-κN,N',N'',N''')nickel(II) perchlorate acetonitrile solvate.

Ou GC, Ng SW - Acta Crystallogr Sect E Struct Rep Online (2010)

Bottom Line: In the crystal structure of the title salt, [Ni(C(3)H(3)O(4))(C(16)H(36)N(4))]ClO(4)·CH(3)CN, the macrocycle folds around the Ni(II) atom, which is also chelated by the carboxyl-ate monoanion.The geometry is a distorted NiN(4)O(2) octa-hedron.The formula units are connected by N-H⋯O hydrogen bonds into centrosymmetric dimers.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the crystal structure of the title salt, [Ni(C(3)H(3)O(4))(C(16)H(36)N(4))]ClO(4)·CH(3)CN, the macrocycle folds around the Ni(II) atom, which is also chelated by the carboxyl-ate monoanion. The geometry is a distorted NiN(4)O(2) octa-hedron. The formula units are connected by N-H⋯O hydrogen bonds into centrosymmetric dimers. Further N-H⋯O and O-H⋯O hydrogen bonds link the complex mol-ecules and the perchlorate ions.

No MeSH data available.


Thermal ellipsoid plot (Barbour, 2001) of [Ni(C16H36N4)(C3H3O4)]+.ClO4-.CH3CN at the 70% probability level; hydrogen atoms are shown as spheres of arbitrary radius.
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Fap1: Thermal ellipsoid plot (Barbour, 2001) of [Ni(C16H36N4)(C3H3O4)]+.ClO4-.CH3CN at the 70% probability level; hydrogen atoms are shown as spheres of arbitrary radius.


(2-Carb-oxy-acetato-κO,O)(rac-5,5,7,12,12,14-hexa-methyl-1,4,8,11-tetra-aza-cyclo-tetra-decane-κN,N',N'',N''')nickel(II) perchlorate acetonitrile solvate.

Ou GC, Ng SW - Acta Crystallogr Sect E Struct Rep Online (2010)

Thermal ellipsoid plot (Barbour, 2001) of [Ni(C16H36N4)(C3H3O4)]+.ClO4-.CH3CN at the 70% probability level; hydrogen atoms are shown as spheres of arbitrary radius.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3009135&req=5

Fap1: Thermal ellipsoid plot (Barbour, 2001) of [Ni(C16H36N4)(C3H3O4)]+.ClO4-.CH3CN at the 70% probability level; hydrogen atoms are shown as spheres of arbitrary radius.
Bottom Line: In the crystal structure of the title salt, [Ni(C(3)H(3)O(4))(C(16)H(36)N(4))]ClO(4)·CH(3)CN, the macrocycle folds around the Ni(II) atom, which is also chelated by the carboxyl-ate monoanion.The geometry is a distorted NiN(4)O(2) octa-hedron.The formula units are connected by N-H⋯O hydrogen bonds into centrosymmetric dimers.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the crystal structure of the title salt, [Ni(C(3)H(3)O(4))(C(16)H(36)N(4))]ClO(4)·CH(3)CN, the macrocycle folds around the Ni(II) atom, which is also chelated by the carboxyl-ate monoanion. The geometry is a distorted NiN(4)O(2) octa-hedron. The formula units are connected by N-H⋯O hydrogen bonds into centrosymmetric dimers. Further N-H⋯O and O-H⋯O hydrogen bonds link the complex mol-ecules and the perchlorate ions.

No MeSH data available.