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{μ(2)-6,6'-Dimeth-oxy-2,2'-[butane-1,4-diylbis(nitrilo-methyl-idyne)]diphenolato}trinitratocopper(II)neodymium(III).

Xing JC, Cui XG, Zhang B, Li WZ - Acta Crystallogr Sect E Struct Rep Online (2010)

Bottom Line: In the title complex, [CuNd(C(20)H(22)N(2)O(4))(NO(3))(3)], the Cu(II) ion is coordinated in a distorted square-planar environment by two O atoms and two N atoms of a tetra-dentate Schiff base ligand.The Nd(III) ion is ten-coordinated by three bis-chelating nitrate groups and four O atoms of the Schiff base ligand.The atoms of one of the nitrato ligands are disordered over two sets of sites, with refined occupancies of 0.567 (13) and 0.433 (17).

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Anesthesiology, the Second Affiliated Hospital, Harbin Medical University, Harbin 150081, People's Republic of China.

ABSTRACT
In the title complex, [CuNd(C(20)H(22)N(2)O(4))(NO(3))(3)], the Cu(II) ion is coordinated in a distorted square-planar environment by two O atoms and two N atoms of a tetra-dentate Schiff base ligand. The Nd(III) ion is ten-coordinated by three bis-chelating nitrate groups and four O atoms of the Schiff base ligand. The atoms of one of the nitrato ligands are disordered over two sets of sites, with refined occupancies of 0.567 (13) and 0.433 (17).

No MeSH data available.


The molecular structure of the title complex, showing 40% probability displacement ellipsoids. All H atoms have been omitted for clarity. The disorder is not shown.
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Fap1: The molecular structure of the title complex, showing 40% probability displacement ellipsoids. All H atoms have been omitted for clarity. The disorder is not shown.


{μ(2)-6,6'-Dimeth-oxy-2,2'-[butane-1,4-diylbis(nitrilo-methyl-idyne)]diphenolato}trinitratocopper(II)neodymium(III).

Xing JC, Cui XG, Zhang B, Li WZ - Acta Crystallogr Sect E Struct Rep Online (2010)

The molecular structure of the title complex, showing 40% probability displacement ellipsoids. All H atoms have been omitted for clarity. The disorder is not shown.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3009133&req=5

Fap1: The molecular structure of the title complex, showing 40% probability displacement ellipsoids. All H atoms have been omitted for clarity. The disorder is not shown.
Bottom Line: In the title complex, [CuNd(C(20)H(22)N(2)O(4))(NO(3))(3)], the Cu(II) ion is coordinated in a distorted square-planar environment by two O atoms and two N atoms of a tetra-dentate Schiff base ligand.The Nd(III) ion is ten-coordinated by three bis-chelating nitrate groups and four O atoms of the Schiff base ligand.The atoms of one of the nitrato ligands are disordered over two sets of sites, with refined occupancies of 0.567 (13) and 0.433 (17).

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Anesthesiology, the Second Affiliated Hospital, Harbin Medical University, Harbin 150081, People's Republic of China.

ABSTRACT
In the title complex, [CuNd(C(20)H(22)N(2)O(4))(NO(3))(3)], the Cu(II) ion is coordinated in a distorted square-planar environment by two O atoms and two N atoms of a tetra-dentate Schiff base ligand. The Nd(III) ion is ten-coordinated by three bis-chelating nitrate groups and four O atoms of the Schiff base ligand. The atoms of one of the nitrato ligands are disordered over two sets of sites, with refined occupancies of 0.567 (13) and 0.433 (17).

No MeSH data available.