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Poly[hexa-μ-acetato-bis-(dimethyl sulfoxide)-trimanganese(II)].

Wan CQ, Xiao NY, Wang ZJ - Acta Crystallogr Sect E Struct Rep Online (2010)

Bottom Line: In the title complex, [Mn(3)(CH(3)CO(2))(6)(C(2)H(6)SO)(2)](n), the Mn(II) ions exhibit similar MnO(6) octa-hedral coordination geometries but with different coordination environments.One type of Mn(II) ion is surrounded by five acetate groups and a terminal dimethyl sulfoxide group, while the other lies on a twofold axis and is coordinated by six O atoms from three symmetry-related acetate ions.The acetate anions exhibit three independent bridging modes, which flexibly bridge the Mn(II) ions along the c-axis direction, forming an infinite chain structure; the chains are further inter-connected through weak C-H⋯O and C-H⋯S hydrogen-bonding inter-actions.

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ABSTRACT
In the title complex, [Mn(3)(CH(3)CO(2))(6)(C(2)H(6)SO)(2)](n), the Mn(II) ions exhibit similar MnO(6) octa-hedral coordination geometries but with different coordination environments. One type of Mn(II) ion is surrounded by five acetate groups and a terminal dimethyl sulfoxide group, while the other lies on a twofold axis and is coordinated by six O atoms from three symmetry-related acetate ions. The acetate anions exhibit three independent bridging modes, which flexibly bridge the Mn(II) ions along the c-axis direction, forming an infinite chain structure; the chains are further inter-connected through weak C-H⋯O and C-H⋯S hydrogen-bonding inter-actions.

No MeSH data available.


Infinite chain of the MnII ions bridged by acetate anions along the c direction in a unit cell. Symmetry code: i -x + 2, y, -z.
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Fap2: Infinite chain of the MnII ions bridged by acetate anions along the c direction in a unit cell. Symmetry code: i -x + 2, y, -z.


Poly[hexa-μ-acetato-bis-(dimethyl sulfoxide)-trimanganese(II)].

Wan CQ, Xiao NY, Wang ZJ - Acta Crystallogr Sect E Struct Rep Online (2010)

Infinite chain of the MnII ions bridged by acetate anions along the c direction in a unit cell. Symmetry code: i -x + 2, y, -z.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3009130&req=5

Fap2: Infinite chain of the MnII ions bridged by acetate anions along the c direction in a unit cell. Symmetry code: i -x + 2, y, -z.
Bottom Line: In the title complex, [Mn(3)(CH(3)CO(2))(6)(C(2)H(6)SO)(2)](n), the Mn(II) ions exhibit similar MnO(6) octa-hedral coordination geometries but with different coordination environments.One type of Mn(II) ion is surrounded by five acetate groups and a terminal dimethyl sulfoxide group, while the other lies on a twofold axis and is coordinated by six O atoms from three symmetry-related acetate ions.The acetate anions exhibit three independent bridging modes, which flexibly bridge the Mn(II) ions along the c-axis direction, forming an infinite chain structure; the chains are further inter-connected through weak C-H⋯O and C-H⋯S hydrogen-bonding inter-actions.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the title complex, [Mn(3)(CH(3)CO(2))(6)(C(2)H(6)SO)(2)](n), the Mn(II) ions exhibit similar MnO(6) octa-hedral coordination geometries but with different coordination environments. One type of Mn(II) ion is surrounded by five acetate groups and a terminal dimethyl sulfoxide group, while the other lies on a twofold axis and is coordinated by six O atoms from three symmetry-related acetate ions. The acetate anions exhibit three independent bridging modes, which flexibly bridge the Mn(II) ions along the c-axis direction, forming an infinite chain structure; the chains are further inter-connected through weak C-H⋯O and C-H⋯S hydrogen-bonding inter-actions.

No MeSH data available.