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10-Methyl-9-[2-(propan-2-yl)phenoxy-carbonyl]-acridinium trifluoro-methane-sulfonate.

Trzybiński D, Krzymiński K, Błażejowski J - Acta Crystallogr Sect E Struct Rep Online (2010)

Bottom Line: The acridine and benzene ring systems are oriented at a dihedral angle of 14.6 (1)°.The carboxyl group is twisted at an angle of 87.6 (1)° relative to the acridine skeleton.The mean planes of adjacent acridine units are parallel or inclined at an angle of 13.4 (1)° in the crystal structure.

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Affiliation: Faculty of Chemistry, University of Gdańsk, J. Sobieskiego 18, 80-952 Gdańsk, Poland.

ABSTRACT
In the crystal of the title compound, C(24)H(22)NO(2) (+)·CF(3)SO(3) (-), adjacent cations and anions are connected through C-H⋯O, C-H⋯F and S-O⋯π inter-actions, while neighboring cations via π-π inter-actions [centroid-centroid distance = 3.962 (2) Å]. The acridine and benzene ring systems are oriented at a dihedral angle of 14.6 (1)°. The carboxyl group is twisted at an angle of 87.6 (1)° relative to the acridine skeleton. The mean planes of adjacent acridine units are parallel or inclined at an angle of 13.4 (1)° in the crystal structure.

No MeSH data available.


The arrangement of the ions in the crystal structure. The C–H···O and C–H···F interactions are represented by dashed lines, the S–O···π and π–π contacts by dotted lines. H atoms not involved in interactions have been omitted. [Symmetry codes: (i) –x + 2, y + 1/2, –z + 1/2; (ii) –x + 2, –y + 1, –z + 1; (iii) –x + 1, –y + 2, –z + 1.]
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Fap2: The arrangement of the ions in the crystal structure. The C–H···O and C–H···F interactions are represented by dashed lines, the S–O···π and π–π contacts by dotted lines. H atoms not involved in interactions have been omitted. [Symmetry codes: (i) –x + 2, y + 1/2, –z + 1/2; (ii) –x + 2, –y + 1, –z + 1; (iii) –x + 1, –y + 2, –z + 1.]


10-Methyl-9-[2-(propan-2-yl)phenoxy-carbonyl]-acridinium trifluoro-methane-sulfonate.

Trzybiński D, Krzymiński K, Błażejowski J - Acta Crystallogr Sect E Struct Rep Online (2010)

The arrangement of the ions in the crystal structure. The C–H···O and C–H···F interactions are represented by dashed lines, the S–O···π and π–π contacts by dotted lines. H atoms not involved in interactions have been omitted. [Symmetry codes: (i) –x + 2, y + 1/2, –z + 1/2; (ii) –x + 2, –y + 1, –z + 1; (iii) –x + 1, –y + 2, –z + 1.]
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3009101&req=5

Fap2: The arrangement of the ions in the crystal structure. The C–H···O and C–H···F interactions are represented by dashed lines, the S–O···π and π–π contacts by dotted lines. H atoms not involved in interactions have been omitted. [Symmetry codes: (i) –x + 2, y + 1/2, –z + 1/2; (ii) –x + 2, –y + 1, –z + 1; (iii) –x + 1, –y + 2, –z + 1.]
Bottom Line: The acridine and benzene ring systems are oriented at a dihedral angle of 14.6 (1)°.The carboxyl group is twisted at an angle of 87.6 (1)° relative to the acridine skeleton.The mean planes of adjacent acridine units are parallel or inclined at an angle of 13.4 (1)° in the crystal structure.

View Article: PubMed Central - HTML - PubMed

Affiliation: Faculty of Chemistry, University of Gdańsk, J. Sobieskiego 18, 80-952 Gdańsk, Poland.

ABSTRACT
In the crystal of the title compound, C(24)H(22)NO(2) (+)·CF(3)SO(3) (-), adjacent cations and anions are connected through C-H⋯O, C-H⋯F and S-O⋯π inter-actions, while neighboring cations via π-π inter-actions [centroid-centroid distance = 3.962 (2) Å]. The acridine and benzene ring systems are oriented at a dihedral angle of 14.6 (1)°. The carboxyl group is twisted at an angle of 87.6 (1)° relative to the acridine skeleton. The mean planes of adjacent acridine units are parallel or inclined at an angle of 13.4 (1)° in the crystal structure.

No MeSH data available.