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trans-Dichloridobis{[4-(dimethyl-amino)-phen-yl]diphenyl-phosphane}palladium(II).

Muller A, Meijboom R - Acta Crystallogr Sect E Struct Rep Online (2010)

Bottom Line: The title compound, trans-[PdCl(2){PPh(2)(4-Me(2)NC(6)H(4))}(2)], crystallizes with the Pd atom on a center of symmetry, resulting in a distorted trans-PdCl(2)P(2) square-planar geometry.Some weak inter-actions are observed between the aromatic rings of adjacent mol-ecules, with an inter-planar distance between two π-stacked rings of 3.505 (3) Å.Intra- and intermolecular C-H⋯Cl hydrogen bonds also occur.

View Article: PubMed Central - HTML - PubMed

Affiliation: Research Centre for Synthesis and Catalysis, Department of Chemistry, University of Johannesburg, PO Box 524 Auckland Park, Johannesburg, 2006, South Africa.

ABSTRACT
The title compound, trans-[PdCl(2){PPh(2)(4-Me(2)NC(6)H(4))}(2)], crystallizes with the Pd atom on a center of symmetry, resulting in a distorted trans-PdCl(2)P(2) square-planar geometry. The Pd-P and Pd-Cl bond lengths are 2.3550 (7) and 2.2906 (7) Å, respectively. Some weak inter-actions are observed between the aromatic rings of adjacent mol-ecules, with an inter-planar distance between two π-stacked rings of 3.505 (3) Å. Intra- and intermolecular C-H⋯Cl hydrogen bonds also occur.

No MeSH data available.


The structure (I), showing 50% probability displacement ellipsoids. For the C atoms, the first digit indicates ring number and the second digit indicates the position of the atom in the ring. Accented lettering indicate atoms generated by symmetry (1 - x,1 - y,1 - z).
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Fap1: The structure (I), showing 50% probability displacement ellipsoids. For the C atoms, the first digit indicates ring number and the second digit indicates the position of the atom in the ring. Accented lettering indicate atoms generated by symmetry (1 - x,1 - y,1 - z).


trans-Dichloridobis{[4-(dimethyl-amino)-phen-yl]diphenyl-phosphane}palladium(II).

Muller A, Meijboom R - Acta Crystallogr Sect E Struct Rep Online (2010)

The structure (I), showing 50% probability displacement ellipsoids. For the C atoms, the first digit indicates ring number and the second digit indicates the position of the atom in the ring. Accented lettering indicate atoms generated by symmetry (1 - x,1 - y,1 - z).
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3009084&req=5

Fap1: The structure (I), showing 50% probability displacement ellipsoids. For the C atoms, the first digit indicates ring number and the second digit indicates the position of the atom in the ring. Accented lettering indicate atoms generated by symmetry (1 - x,1 - y,1 - z).
Bottom Line: The title compound, trans-[PdCl(2){PPh(2)(4-Me(2)NC(6)H(4))}(2)], crystallizes with the Pd atom on a center of symmetry, resulting in a distorted trans-PdCl(2)P(2) square-planar geometry.Some weak inter-actions are observed between the aromatic rings of adjacent mol-ecules, with an inter-planar distance between two π-stacked rings of 3.505 (3) Å.Intra- and intermolecular C-H⋯Cl hydrogen bonds also occur.

View Article: PubMed Central - HTML - PubMed

Affiliation: Research Centre for Synthesis and Catalysis, Department of Chemistry, University of Johannesburg, PO Box 524 Auckland Park, Johannesburg, 2006, South Africa.

ABSTRACT
The title compound, trans-[PdCl(2){PPh(2)(4-Me(2)NC(6)H(4))}(2)], crystallizes with the Pd atom on a center of symmetry, resulting in a distorted trans-PdCl(2)P(2) square-planar geometry. The Pd-P and Pd-Cl bond lengths are 2.3550 (7) and 2.2906 (7) Å, respectively. Some weak inter-actions are observed between the aromatic rings of adjacent mol-ecules, with an inter-planar distance between two π-stacked rings of 3.505 (3) Å. Intra- and intermolecular C-H⋯Cl hydrogen bonds also occur.

No MeSH data available.