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Acetonitrile-bis-(2,9-dimethyl-1,10-phen-an-throline)copper(II) bis-(tetra-fluorido-borate).

Watton SP - Acta Crystallogr Sect E Struct Rep Online (2010)

Bottom Line: Acta Cryst.E65, m585-m586].One of the four BF(4) (-) counter-ions is disordered, with a refined site occupancy of 0.8615 (17):0.1385 (17).

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Affiliation: Department of Chemistry and Biochemistry, Central Connecticut State University, 1615 Stanley Street, New Britain, CT 06050, USA.

ABSTRACT
The title compound, [Cu(CH(3)CN)(C(12)H(12)N(2))(2)](BF(4))(2), crystallizes with two copper-containing cations and four tetra-fluoro-borate anions in the asymmetric unit. The structure represents a second crystal form of the salt, the first being an acetonitrile solvate [Watton (2009 ▶). Acta Cryst. E65, m585-m586]. The complex cation has a distorted trigonal-bipyramidal geometry, whereas the previous structure exhibits a distorted square-pyramidal geometry. One of the four BF(4) (-) counter-ions is disordered, with a refined site occupancy of 0.8615 (17):0.1385 (17).

No MeSH data available.


ORTEP of Cation 2 showing atom numbering scheme. Hydrogen atoms omitted for clarity and thermal ellipsoids drawn at 50% probability level.
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Fap2: ORTEP of Cation 2 showing atom numbering scheme. Hydrogen atoms omitted for clarity and thermal ellipsoids drawn at 50% probability level.


Acetonitrile-bis-(2,9-dimethyl-1,10-phen-an-throline)copper(II) bis-(tetra-fluorido-borate).

Watton SP - Acta Crystallogr Sect E Struct Rep Online (2010)

ORTEP of Cation 2 showing atom numbering scheme. Hydrogen atoms omitted for clarity and thermal ellipsoids drawn at 50% probability level.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3009076&req=5

Fap2: ORTEP of Cation 2 showing atom numbering scheme. Hydrogen atoms omitted for clarity and thermal ellipsoids drawn at 50% probability level.
Bottom Line: Acta Cryst.E65, m585-m586].One of the four BF(4) (-) counter-ions is disordered, with a refined site occupancy of 0.8615 (17):0.1385 (17).

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry and Biochemistry, Central Connecticut State University, 1615 Stanley Street, New Britain, CT 06050, USA.

ABSTRACT
The title compound, [Cu(CH(3)CN)(C(12)H(12)N(2))(2)](BF(4))(2), crystallizes with two copper-containing cations and four tetra-fluoro-borate anions in the asymmetric unit. The structure represents a second crystal form of the salt, the first being an acetonitrile solvate [Watton (2009 ▶). Acta Cryst. E65, m585-m586]. The complex cation has a distorted trigonal-bipyramidal geometry, whereas the previous structure exhibits a distorted square-pyramidal geometry. One of the four BF(4) (-) counter-ions is disordered, with a refined site occupancy of 0.8615 (17):0.1385 (17).

No MeSH data available.