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Morpholinium styphnate.

Kalaivani D, Malarvizhi R - Acta Crystallogr Sect E Struct Rep Online (2010)

Bottom Line: An intra-molecular O-H⋯O hydrogen bond occurs in the anion.The morpholinium cation has a slightly distorted chair conformation.In the crystal, the components are linked by simple N-H⋯O and trifurcated N-H⋯(O,O,O) hydrogen bonds.

View Article: PubMed Central - HTML - PubMed

Affiliation: PG & Research Department of Chemistry, Seethalakshmi Ramaswami College, Tiruchirappalli 620 002, Tamil Nadu, India.

ABSTRACT
In the title mol-ecular salt (systematic name: morpholinium 3-hy-droxy-2,4,6-trinitro-phenolate), C(4)H(10)NO(+)·C(6)H(2)N(3)O(8) (-), two of the nitro groups of the anion are close to parallel with the plane of the benzene ring [dihedral angles = 3.46 (9) and 11.60 (10)°] and one is almost perpendicular [dihedral angle = 82.23 (8)°]. An intra-molecular O-H⋯O hydrogen bond occurs in the anion. The morpholinium cation has a slightly distorted chair conformation. In the crystal, the components are linked by simple N-H⋯O and trifurcated N-H⋯(O,O,O) hydrogen bonds.

No MeSH data available.


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The packing view of the adduct
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Fap3: The packing view of the adduct


Morpholinium styphnate.

Kalaivani D, Malarvizhi R - Acta Crystallogr Sect E Struct Rep Online (2010)

The packing view of the adduct
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3009074&req=5

Fap3: The packing view of the adduct
Bottom Line: An intra-molecular O-H⋯O hydrogen bond occurs in the anion.The morpholinium cation has a slightly distorted chair conformation.In the crystal, the components are linked by simple N-H⋯O and trifurcated N-H⋯(O,O,O) hydrogen bonds.

View Article: PubMed Central - HTML - PubMed

Affiliation: PG & Research Department of Chemistry, Seethalakshmi Ramaswami College, Tiruchirappalli 620 002, Tamil Nadu, India.

ABSTRACT
In the title mol-ecular salt (systematic name: morpholinium 3-hy-droxy-2,4,6-trinitro-phenolate), C(4)H(10)NO(+)·C(6)H(2)N(3)O(8) (-), two of the nitro groups of the anion are close to parallel with the plane of the benzene ring [dihedral angles = 3.46 (9) and 11.60 (10)°] and one is almost perpendicular [dihedral angle = 82.23 (8)°]. An intra-molecular O-H⋯O hydrogen bond occurs in the anion. The morpholinium cation has a slightly distorted chair conformation. In the crystal, the components are linked by simple N-H⋯O and trifurcated N-H⋯(O,O,O) hydrogen bonds.

No MeSH data available.


Related in: MedlinePlus