Limits...
trans-Dichlorido-bis-[tris(4-meth-oxy-phenyl)-phosphane]palladium(II) toluene solvate.

Muller A, Meijboom R - Acta Crystallogr Sect E Struct Rep Online (2010)

Bottom Line: In the title compound, trans-[PdCl(2){P(4-MeOC(6)H(4))(3)}(2)]·C(7)H(8), the Pd(II) atom lies on a center of symmetry, resulting in a distorted trans-square planar geometry.In the crystal, weak C-H⋯O inter-actions are observed between the aromatic rings of adjacent mol-ecules.The toluene solvate molecule is equally disordered over two sets of sites.

View Article: PubMed Central - HTML - PubMed

Affiliation: Research Centre for Synthesis and Catalysis, Department of Chemistry, University of Johannesburg, PO Box 524 Auckland Park, Johannesburg, 2006, South Africa.

ABSTRACT
In the title compound, trans-[PdCl(2){P(4-MeOC(6)H(4))(3)}(2)]·C(7)H(8), the Pd(II) atom lies on a center of symmetry, resulting in a distorted trans-square planar geometry. The Pd-P and Pd-Cl bond lengths are 2.3409 (4) and 2.2981 (4) Å, respectively. An intra-molecular C-H⋯Cl hydrogen bond occurs. In the crystal, weak C-H⋯O inter-actions are observed between the aromatic rings of adjacent mol-ecules. The toluene solvate molecule is equally disordered over two sets of sites.

No MeSH data available.


The structure (I), showing 50% probability displacement ellipsoids. For the C atoms, the first digit indicates ring number and the second digit indicates the position of the atom in the ring. Accented lettering indicate atoms generated by symmetry (1 - x,1 - y,1 - z).
© Copyright Policy - open-access
Related In: Results  -  Collection

License
getmorefigures.php?uid=PMC3009065&req=5

Fap1: The structure (I), showing 50% probability displacement ellipsoids. For the C atoms, the first digit indicates ring number and the second digit indicates the position of the atom in the ring. Accented lettering indicate atoms generated by symmetry (1 - x,1 - y,1 - z).


trans-Dichlorido-bis-[tris(4-meth-oxy-phenyl)-phosphane]palladium(II) toluene solvate.

Muller A, Meijboom R - Acta Crystallogr Sect E Struct Rep Online (2010)

The structure (I), showing 50% probability displacement ellipsoids. For the C atoms, the first digit indicates ring number and the second digit indicates the position of the atom in the ring. Accented lettering indicate atoms generated by symmetry (1 - x,1 - y,1 - z).
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3009065&req=5

Fap1: The structure (I), showing 50% probability displacement ellipsoids. For the C atoms, the first digit indicates ring number and the second digit indicates the position of the atom in the ring. Accented lettering indicate atoms generated by symmetry (1 - x,1 - y,1 - z).
Bottom Line: In the title compound, trans-[PdCl(2){P(4-MeOC(6)H(4))(3)}(2)]·C(7)H(8), the Pd(II) atom lies on a center of symmetry, resulting in a distorted trans-square planar geometry.In the crystal, weak C-H⋯O inter-actions are observed between the aromatic rings of adjacent mol-ecules.The toluene solvate molecule is equally disordered over two sets of sites.

View Article: PubMed Central - HTML - PubMed

Affiliation: Research Centre for Synthesis and Catalysis, Department of Chemistry, University of Johannesburg, PO Box 524 Auckland Park, Johannesburg, 2006, South Africa.

ABSTRACT
In the title compound, trans-[PdCl(2){P(4-MeOC(6)H(4))(3)}(2)]·C(7)H(8), the Pd(II) atom lies on a center of symmetry, resulting in a distorted trans-square planar geometry. The Pd-P and Pd-Cl bond lengths are 2.3409 (4) and 2.2981 (4) Å, respectively. An intra-molecular C-H⋯Cl hydrogen bond occurs. In the crystal, weak C-H⋯O inter-actions are observed between the aromatic rings of adjacent mol-ecules. The toluene solvate molecule is equally disordered over two sets of sites.

No MeSH data available.