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(μ-4,4'-Bipyridine-κN:N')bis-[bis-(N,N-dimethyl-dithio-carbamato-κS,S')zinc(II)].

Zha MQ, Li X, Bing Y, Lu Y - Acta Crystallogr Sect E Struct Rep Online (2010)

Bottom Line: The title dinuclear Zn(II) complex, [Zn(2)(C(3)H(6)NS(2))(4)(C(10)H(8)N(2))], is centrosymmetric; the mid-point of the C-C bond linking the two pyridine rings is located on an inversion center.The pyridine N atom coordinates to the Zn(II) cation, which is also chelated by two dimethyl-dithio-carbamate anions, giving a trigonal-bipyramidal ZnNS(4) geometry.Weak inter-molecular C-H⋯S hydrogen bonding is present in the crystal structure.

View Article: PubMed Central - HTML - PubMed

Affiliation: Faculty of Materials Science and Chemical Engineering, Ningbo University, Ningbo Zhejiang 315211, People's Republic of China.

ABSTRACT
The title dinuclear Zn(II) complex, [Zn(2)(C(3)H(6)NS(2))(4)(C(10)H(8)N(2))], is centrosymmetric; the mid-point of the C-C bond linking the two pyridine rings is located on an inversion center. The pyridine N atom coordinates to the Zn(II) cation, which is also chelated by two dimethyl-dithio-carbamate anions, giving a trigonal-bipyramidal ZnNS(4) geometry. Weak inter-molecular C-H⋯S hydrogen bonding is present in the crystal structure.

No MeSH data available.


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Unit-cell contents for (I) viewed in projection down the b axis.
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Fap3: Unit-cell contents for (I) viewed in projection down the b axis.


(μ-4,4'-Bipyridine-κN:N')bis-[bis-(N,N-dimethyl-dithio-carbamato-κS,S')zinc(II)].

Zha MQ, Li X, Bing Y, Lu Y - Acta Crystallogr Sect E Struct Rep Online (2010)

Unit-cell contents for (I) viewed in projection down the b axis.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3009053&req=5

Fap3: Unit-cell contents for (I) viewed in projection down the b axis.
Bottom Line: The title dinuclear Zn(II) complex, [Zn(2)(C(3)H(6)NS(2))(4)(C(10)H(8)N(2))], is centrosymmetric; the mid-point of the C-C bond linking the two pyridine rings is located on an inversion center.The pyridine N atom coordinates to the Zn(II) cation, which is also chelated by two dimethyl-dithio-carbamate anions, giving a trigonal-bipyramidal ZnNS(4) geometry.Weak inter-molecular C-H⋯S hydrogen bonding is present in the crystal structure.

View Article: PubMed Central - HTML - PubMed

Affiliation: Faculty of Materials Science and Chemical Engineering, Ningbo University, Ningbo Zhejiang 315211, People's Republic of China.

ABSTRACT
The title dinuclear Zn(II) complex, [Zn(2)(C(3)H(6)NS(2))(4)(C(10)H(8)N(2))], is centrosymmetric; the mid-point of the C-C bond linking the two pyridine rings is located on an inversion center. The pyridine N atom coordinates to the Zn(II) cation, which is also chelated by two dimethyl-dithio-carbamate anions, giving a trigonal-bipyramidal ZnNS(4) geometry. Weak inter-molecular C-H⋯S hydrogen bonding is present in the crystal structure.

No MeSH data available.


Related in: MedlinePlus