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catena-Poly[[dipyridine-cadmium(II)]-μ-5-amino-2,4,6-triiodo-isophthalato].

Zou Y - Acta Crystallogr Sect E Struct Rep Online (2010)

Bottom Line: The structure contains a four-coordinate Cd(2+ )ion in a distorted tetra-hedral geometry, which lies on a crystallographic twofold rotation axis.The Cd(2+ )ion is bonded to two N atoms from two pyridine ligands and two carboxyl-ate O atoms from two 5-amino-2,4,6-triiodo-isophthalate anions.The Cd-O distances are 2.429 (5) and 2.305 (5) Å and the Cd-N distance is 2.236 (8) Å.

View Article: PubMed Central - HTML - PubMed

Affiliation: Chemistry Department, Zhejiang Sci-Tech University, Hangzhou, 310018, People's Republic of China.

ABSTRACT
The hydro-thermal reaction of cadmium(II) nitrate with 5-amino-2,4,6-triiodo-isophthalic acid and pyridine in DMF solution leads to the formation of the title compound, [Cd(C(8)H(2)I(3)NO(4))(C(5)H(5)N)(2)](n). The structure contains a four-coordinate Cd(2+ )ion in a distorted tetra-hedral geometry, which lies on a crystallographic twofold rotation axis. The Cd(2+ )ion is bonded to two N atoms from two pyridine ligands and two carboxyl-ate O atoms from two 5-amino-2,4,6-triiodo-isophthalate anions. The Cd-O distances are 2.429 (5) and 2.305 (5) Å and the Cd-N distance is 2.236 (8) Å. The two carboxyl-ate groups of individual 5-amino-2,4,6-triiodo-isophthalate anions act as a bridge to the Cd(2+) atoms. leading to a chain structure along the c axis.

No MeSH data available.


ORTEP plot of the title complex with atom numbering scheme. Thermal ellipsoids are drawn at 40% probability level.
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Fap1: ORTEP plot of the title complex with atom numbering scheme. Thermal ellipsoids are drawn at 40% probability level.


catena-Poly[[dipyridine-cadmium(II)]-μ-5-amino-2,4,6-triiodo-isophthalato].

Zou Y - Acta Crystallogr Sect E Struct Rep Online (2010)

ORTEP plot of the title complex with atom numbering scheme. Thermal ellipsoids are drawn at 40% probability level.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3009045&req=5

Fap1: ORTEP plot of the title complex with atom numbering scheme. Thermal ellipsoids are drawn at 40% probability level.
Bottom Line: The structure contains a four-coordinate Cd(2+ )ion in a distorted tetra-hedral geometry, which lies on a crystallographic twofold rotation axis.The Cd(2+ )ion is bonded to two N atoms from two pyridine ligands and two carboxyl-ate O atoms from two 5-amino-2,4,6-triiodo-isophthalate anions.The Cd-O distances are 2.429 (5) and 2.305 (5) Å and the Cd-N distance is 2.236 (8) Å.

View Article: PubMed Central - HTML - PubMed

Affiliation: Chemistry Department, Zhejiang Sci-Tech University, Hangzhou, 310018, People's Republic of China.

ABSTRACT
The hydro-thermal reaction of cadmium(II) nitrate with 5-amino-2,4,6-triiodo-isophthalic acid and pyridine in DMF solution leads to the formation of the title compound, [Cd(C(8)H(2)I(3)NO(4))(C(5)H(5)N)(2)](n). The structure contains a four-coordinate Cd(2+ )ion in a distorted tetra-hedral geometry, which lies on a crystallographic twofold rotation axis. The Cd(2+ )ion is bonded to two N atoms from two pyridine ligands and two carboxyl-ate O atoms from two 5-amino-2,4,6-triiodo-isophthalate anions. The Cd-O distances are 2.429 (5) and 2.305 (5) Å and the Cd-N distance is 2.236 (8) Å. The two carboxyl-ate groups of individual 5-amino-2,4,6-triiodo-isophthalate anions act as a bridge to the Cd(2+) atoms. leading to a chain structure along the c axis.

No MeSH data available.