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Diaqua-bis-(1,10-phenanthroline-κN,N')manganese(II) sulfate hexa-hydrate.

Zhang C, Zhu HL - Acta Crystallogr Sect E Struct Rep Online (2010)

Bottom Line: In the title compound, [Mn(C(12)H(8)N(2))(2)(H(2)O)(2)]SO(4)·6H(2)O, the complex cations assemble into positively charged sheets parallel to (010) via inter-molecular π-π stacking inter-actions with a mean interplanar distance of 3.410 (6) along [100] and 3.465 (5) Å along [001].The sulfate anions and uncoordinated water mol-ecules are inter-connected between these layers by hydrogen bonds, forming negatively charged layers which are linked to the positive layers through O-H⋯O hydrogen bonds, forming a three-dimensional architecture.Both the positive and negative sheets are stacked along [010] in an ⋯ABAB⋯ sequence, the A layers being shifted by 1/2a along [100] with respect to the B layers.

View Article: PubMed Central - HTML - PubMed

Affiliation: State Key Laboratory Base of Novel Functional Materials and Preparation Science, Center of Applied Solid State Chemistry Research, Ningbo University, Ningbo, Zhejiang 315211, People's Republic of China.

ABSTRACT
In the title compound, [Mn(C(12)H(8)N(2))(2)(H(2)O)(2)]SO(4)·6H(2)O, the complex cations assemble into positively charged sheets parallel to (010) via inter-molecular π-π stacking inter-actions with a mean interplanar distance of 3.410 (6) along [100] and 3.465 (5) Å along [001]. The sulfate anions and uncoordinated water mol-ecules are inter-connected between these layers by hydrogen bonds, forming negatively charged layers which are linked to the positive layers through O-H⋯O hydrogen bonds, forming a three-dimensional architecture. Both the positive and negative sheets are stacked along [010] in an ⋯ABAB⋯ sequence, the A layers being shifted by 1/2a along [100] with respect to the B layers. One of the uncoordinated water molecules is equally disordered over two positions.

No MeSH data available.


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The positively charged two-dimensional layer of the complex cations pallel to (010).
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Fap2: The positively charged two-dimensional layer of the complex cations pallel to (010).


Diaqua-bis-(1,10-phenanthroline-κN,N')manganese(II) sulfate hexa-hydrate.

Zhang C, Zhu HL - Acta Crystallogr Sect E Struct Rep Online (2010)

The positively charged two-dimensional layer of the complex cations pallel to (010).
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3009039&req=5

Fap2: The positively charged two-dimensional layer of the complex cations pallel to (010).
Bottom Line: In the title compound, [Mn(C(12)H(8)N(2))(2)(H(2)O)(2)]SO(4)·6H(2)O, the complex cations assemble into positively charged sheets parallel to (010) via inter-molecular π-π stacking inter-actions with a mean interplanar distance of 3.410 (6) along [100] and 3.465 (5) Å along [001].The sulfate anions and uncoordinated water mol-ecules are inter-connected between these layers by hydrogen bonds, forming negatively charged layers which are linked to the positive layers through O-H⋯O hydrogen bonds, forming a three-dimensional architecture.Both the positive and negative sheets are stacked along [010] in an ⋯ABAB⋯ sequence, the A layers being shifted by 1/2a along [100] with respect to the B layers.

View Article: PubMed Central - HTML - PubMed

Affiliation: State Key Laboratory Base of Novel Functional Materials and Preparation Science, Center of Applied Solid State Chemistry Research, Ningbo University, Ningbo, Zhejiang 315211, People's Republic of China.

ABSTRACT
In the title compound, [Mn(C(12)H(8)N(2))(2)(H(2)O)(2)]SO(4)·6H(2)O, the complex cations assemble into positively charged sheets parallel to (010) via inter-molecular π-π stacking inter-actions with a mean interplanar distance of 3.410 (6) along [100] and 3.465 (5) Å along [001]. The sulfate anions and uncoordinated water mol-ecules are inter-connected between these layers by hydrogen bonds, forming negatively charged layers which are linked to the positive layers through O-H⋯O hydrogen bonds, forming a three-dimensional architecture. Both the positive and negative sheets are stacked along [010] in an ⋯ABAB⋯ sequence, the A layers being shifted by 1/2a along [100] with respect to the B layers. One of the uncoordinated water molecules is equally disordered over two positions.

No MeSH data available.


Related in: MedlinePlus