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2-Chloro-N-(4-meth-oxy-phen-yl)benzamide.

Saeed A, Simpson J - Acta Crystallogr Sect E Struct Rep Online (2010)

Bottom Line: The N-H bond is anti to the 2-chloro substituent of the aniline ring.In the crystal structure, inter-molecular N-H⋯O hydrogen bonds form C(4) chains augmented by a weak C-H⋯O inter-action involving an ortho H atom of the meth-oxy benzene ring that generates an R(2) (1)(6) motif.The chains stack the mol-ecules into columns down the b axis.

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ABSTRACT
In the title compound, C(14)H(12)ClNO(2), the chloro- and meth-oxy-substituted benzene rings are close to orthogonal [dihedral angle = 79.20 (3)°]. These rings also make angles of 45.9 (3) and 33.5 (3)° with the amide -CONH- unit. The meth-oxy substituent lies close to the meth-oxy-benzene ring plane, with a maximum deviation of 0.142 (3) Å for the methyl C atom. The N-H bond is anti to the 2-chloro substituent of the aniline ring. In the crystal structure, inter-molecular N-H⋯O hydrogen bonds form C(4) chains augmented by a weak C-H⋯O inter-action involving an ortho H atom of the meth-oxy benzene ring that generates an R(2) (1)(6) motif. The chains stack the mol-ecules into columns down the b axis. Adjacent columns are linked by additional C-H⋯O and C-H⋯π contacts, generating a three-dimensional network.

No MeSH data available.


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Crystal packing for (I) viewed down the b axis with hydrogen bonds drawn as dashed lines.
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Fap3: Crystal packing for (I) viewed down the b axis with hydrogen bonds drawn as dashed lines.


2-Chloro-N-(4-meth-oxy-phen-yl)benzamide.

Saeed A, Simpson J - Acta Crystallogr Sect E Struct Rep Online (2010)

Crystal packing for (I) viewed down the b axis with hydrogen bonds drawn as dashed lines.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3009019&req=5

Fap3: Crystal packing for (I) viewed down the b axis with hydrogen bonds drawn as dashed lines.
Bottom Line: The N-H bond is anti to the 2-chloro substituent of the aniline ring.In the crystal structure, inter-molecular N-H⋯O hydrogen bonds form C(4) chains augmented by a weak C-H⋯O inter-action involving an ortho H atom of the meth-oxy benzene ring that generates an R(2) (1)(6) motif.The chains stack the mol-ecules into columns down the b axis.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the title compound, C(14)H(12)ClNO(2), the chloro- and meth-oxy-substituted benzene rings are close to orthogonal [dihedral angle = 79.20 (3)°]. These rings also make angles of 45.9 (3) and 33.5 (3)° with the amide -CONH- unit. The meth-oxy substituent lies close to the meth-oxy-benzene ring plane, with a maximum deviation of 0.142 (3) Å for the methyl C atom. The N-H bond is anti to the 2-chloro substituent of the aniline ring. In the crystal structure, inter-molecular N-H⋯O hydrogen bonds form C(4) chains augmented by a weak C-H⋯O inter-action involving an ortho H atom of the meth-oxy benzene ring that generates an R(2) (1)(6) motif. The chains stack the mol-ecules into columns down the b axis. Adjacent columns are linked by additional C-H⋯O and C-H⋯π contacts, generating a three-dimensional network.

No MeSH data available.


Related in: MedlinePlus