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Chloridodimeth-yl(thio-semi-carbazide)tin(IV) chloride.

Cortes C L, Burgos C AE, Okio CK - Acta Crystallogr Sect E Struct Rep Online (2010)

Bottom Line: In the title salt, [Sn(CH(3))(2)Cl(CH(4)N(3)S)]Cl, the Sn(IV) atom is five-coordinated in a distorted trigonal-bipyramidal geometry with two methyl groups and one S atom in the equatorial plane, and one N atom and one Cl atom occupying the apical positions.In the crystal, mol-ecules are linked by inter-molecular N-H⋯S hydrogen bonds with set graph-motif C(4) along [010].N-H⋯ Cl hydrogen bonds with graph-set motif D(2) and D(3) (3)(10) link cations and anions.

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Affiliation: Departamento de Quimíca, Universidad Nacional de Colombia, Sede Bogotá, Bogotá, Colombia.

ABSTRACT
In the title salt, [Sn(CH(3))(2)Cl(CH(4)N(3)S)]Cl, the Sn(IV) atom is five-coordinated in a distorted trigonal-bipyramidal geometry with two methyl groups and one S atom in the equatorial plane, and one N atom and one Cl atom occupying the apical positions. In the crystal, mol-ecules are linked by inter-molecular N-H⋯S hydrogen bonds with set graph-motif C(4) along [010]. N-H⋯ Cl hydrogen bonds with graph-set motif D(2) and D(3) (3)(10) link cations and anions.

No MeSH data available.


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Unit-cell packing diagram for (I). Hydrogen bonds are shown as dashed lines.
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Fap2: Unit-cell packing diagram for (I). Hydrogen bonds are shown as dashed lines.


Chloridodimeth-yl(thio-semi-carbazide)tin(IV) chloride.

Cortes C L, Burgos C AE, Okio CK - Acta Crystallogr Sect E Struct Rep Online (2010)

Unit-cell packing diagram for (I). Hydrogen bonds are shown as dashed lines.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3009011&req=5

Fap2: Unit-cell packing diagram for (I). Hydrogen bonds are shown as dashed lines.
Bottom Line: In the title salt, [Sn(CH(3))(2)Cl(CH(4)N(3)S)]Cl, the Sn(IV) atom is five-coordinated in a distorted trigonal-bipyramidal geometry with two methyl groups and one S atom in the equatorial plane, and one N atom and one Cl atom occupying the apical positions.In the crystal, mol-ecules are linked by inter-molecular N-H⋯S hydrogen bonds with set graph-motif C(4) along [010].N-H⋯ Cl hydrogen bonds with graph-set motif D(2) and D(3) (3)(10) link cations and anions.

View Article: PubMed Central - HTML - PubMed

Affiliation: Departamento de Quimíca, Universidad Nacional de Colombia, Sede Bogotá, Bogotá, Colombia.

ABSTRACT
In the title salt, [Sn(CH(3))(2)Cl(CH(4)N(3)S)]Cl, the Sn(IV) atom is five-coordinated in a distorted trigonal-bipyramidal geometry with two methyl groups and one S atom in the equatorial plane, and one N atom and one Cl atom occupying the apical positions. In the crystal, mol-ecules are linked by inter-molecular N-H⋯S hydrogen bonds with set graph-motif C(4) along [010]. N-H⋯ Cl hydrogen bonds with graph-set motif D(2) and D(3) (3)(10) link cations and anions.

No MeSH data available.


Related in: MedlinePlus