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N,N'-Bis[(E)-(5-chloro-2-thienyl)methyl-idene]ethane-1,2-diamine.

Prasath R, Bhavana P, Ng SW, Tiekink ER - Acta Crystallogr Sect E Struct Rep Online (2010)

Bottom Line: The full mol-ecule of the title compound, C(12)H(10)Cl(2)N(2)S(2), is generated by the application of a centre of inversion.The thio-phene and imine residues are co-planar [the N-C-C-S torsion angle is -2.5 (4)°] and the conformation about the imine bond [1.268 (4) Å] is E.Supra-molecular arrays are formed in the bc plane via C-Cl⋯π inter-actions and these stack along the a axis.

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ABSTRACT
The full mol-ecule of the title compound, C(12)H(10)Cl(2)N(2)S(2), is generated by the application of a centre of inversion. The thio-phene and imine residues are co-planar [the N-C-C-S torsion angle is -2.5 (4)°] and the conformation about the imine bond [1.268 (4) Å] is E. Supra-molecular arrays are formed in the bc plane via C-Cl⋯π inter-actions and these stack along the a axis.

No MeSH data available.


Related in: MedlinePlus

A view of the supramolecular 2-D array in the bc plane mediated by C—Cl···π interactions (purple dashed lines).
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Fap2: A view of the supramolecular 2-D array in the bc plane mediated by C—Cl···π interactions (purple dashed lines).


N,N'-Bis[(E)-(5-chloro-2-thienyl)methyl-idene]ethane-1,2-diamine.

Prasath R, Bhavana P, Ng SW, Tiekink ER - Acta Crystallogr Sect E Struct Rep Online (2010)

A view of the supramolecular 2-D array in the bc plane mediated by C—Cl···π interactions (purple dashed lines).
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3009004&req=5

Fap2: A view of the supramolecular 2-D array in the bc plane mediated by C—Cl···π interactions (purple dashed lines).
Bottom Line: The full mol-ecule of the title compound, C(12)H(10)Cl(2)N(2)S(2), is generated by the application of a centre of inversion.The thio-phene and imine residues are co-planar [the N-C-C-S torsion angle is -2.5 (4)°] and the conformation about the imine bond [1.268 (4) Å] is E.Supra-molecular arrays are formed in the bc plane via C-Cl⋯π inter-actions and these stack along the a axis.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
The full mol-ecule of the title compound, C(12)H(10)Cl(2)N(2)S(2), is generated by the application of a centre of inversion. The thio-phene and imine residues are co-planar [the N-C-C-S torsion angle is -2.5 (4)°] and the conformation about the imine bond [1.268 (4) Å] is E. Supra-molecular arrays are formed in the bc plane via C-Cl⋯π inter-actions and these stack along the a axis.

No MeSH data available.


Related in: MedlinePlus