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catena-Poly[[[(triphenyl-phosphane)copper(I)]-di-μ-iodido-[(triphenyl-phosphane)copper(I)]-μ-[3,6-bis-(4-pyrid-yl)-1,2,4,5-tetra-zine]] acetonitrile disolvate].

Zhang J - Acta Crystallogr Sect E Struct Rep Online (2010)

Bottom Line: The title compound, {[Cu(2)I(2)(C(12)H(8)N(6))(C(18)H(15)P)(2)]·2CH(3)CN}(n), contains centrosymmetric dinuclear Cu(2)I(2)(PPh(3))(2) units bridged by 3,6-bis-(4-pyrid-yl)-1,2,4,5-tetra-zine ligands lying also across crystallographic inversion centers, giving a chain structure in the ab plane.The distorted tetra-hedral Cu(I) atoms in the dinuclear unit are coordinated by two bridging iodide anions, one pyridine N atom from the substituted tetra-zine ligand and one terminal triphenyl-phosphine P-atom donor.The Cu⋯Cu distance is 2.8293 (12) Å, implying a weak Cu⋯Cu inter-action.

View Article: PubMed Central - HTML - PubMed

Affiliation: Molecular Materials Research Center, Scientific Research Academy, School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013, People's Republic of China.

ABSTRACT
The title compound, {[Cu(2)I(2)(C(12)H(8)N(6))(C(18)H(15)P)(2)]·2CH(3)CN}(n), contains centrosymmetric dinuclear Cu(2)I(2)(PPh(3))(2) units bridged by 3,6-bis-(4-pyrid-yl)-1,2,4,5-tetra-zine ligands lying also across crystallographic inversion centers, giving a chain structure in the ab plane. The distorted tetra-hedral Cu(I) atoms in the dinuclear unit are coordinated by two bridging iodide anions, one pyridine N atom from the substituted tetra-zine ligand and one terminal triphenyl-phosphine P-atom donor. The Cu⋯Cu distance is 2.8293 (12) Å, implying a weak Cu⋯Cu inter-action.

No MeSH data available.


Related in: MedlinePlus

The molecular structure of a portion of the title compound, with atom labels and 30% probability displacement ellipsoids. All H atoms have been omitted. Symmetry codes: (i) -x, -y, -z; (ii) -x + 1, -y - 1, -z.
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getmorefigures.php?uid=PMC3008982&req=5

Fap1: The molecular structure of a portion of the title compound, with atom labels and 30% probability displacement ellipsoids. All H atoms have been omitted. Symmetry codes: (i) -x, -y, -z; (ii) -x + 1, -y - 1, -z.


catena-Poly[[[(triphenyl-phosphane)copper(I)]-di-μ-iodido-[(triphenyl-phosphane)copper(I)]-μ-[3,6-bis-(4-pyrid-yl)-1,2,4,5-tetra-zine]] acetonitrile disolvate].

Zhang J - Acta Crystallogr Sect E Struct Rep Online (2010)

The molecular structure of a portion of the title compound, with atom labels and 30% probability displacement ellipsoids. All H atoms have been omitted. Symmetry codes: (i) -x, -y, -z; (ii) -x + 1, -y - 1, -z.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3008982&req=5

Fap1: The molecular structure of a portion of the title compound, with atom labels and 30% probability displacement ellipsoids. All H atoms have been omitted. Symmetry codes: (i) -x, -y, -z; (ii) -x + 1, -y - 1, -z.
Bottom Line: The title compound, {[Cu(2)I(2)(C(12)H(8)N(6))(C(18)H(15)P)(2)]·2CH(3)CN}(n), contains centrosymmetric dinuclear Cu(2)I(2)(PPh(3))(2) units bridged by 3,6-bis-(4-pyrid-yl)-1,2,4,5-tetra-zine ligands lying also across crystallographic inversion centers, giving a chain structure in the ab plane.The distorted tetra-hedral Cu(I) atoms in the dinuclear unit are coordinated by two bridging iodide anions, one pyridine N atom from the substituted tetra-zine ligand and one terminal triphenyl-phosphine P-atom donor.The Cu⋯Cu distance is 2.8293 (12) Å, implying a weak Cu⋯Cu inter-action.

View Article: PubMed Central - HTML - PubMed

Affiliation: Molecular Materials Research Center, Scientific Research Academy, School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013, People's Republic of China.

ABSTRACT
The title compound, {[Cu(2)I(2)(C(12)H(8)N(6))(C(18)H(15)P)(2)]·2CH(3)CN}(n), contains centrosymmetric dinuclear Cu(2)I(2)(PPh(3))(2) units bridged by 3,6-bis-(4-pyrid-yl)-1,2,4,5-tetra-zine ligands lying also across crystallographic inversion centers, giving a chain structure in the ab plane. The distorted tetra-hedral Cu(I) atoms in the dinuclear unit are coordinated by two bridging iodide anions, one pyridine N atom from the substituted tetra-zine ligand and one terminal triphenyl-phosphine P-atom donor. The Cu⋯Cu distance is 2.8293 (12) Å, implying a weak Cu⋯Cu inter-action.

No MeSH data available.


Related in: MedlinePlus