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2-Ferrocenyl-N-(6-methyl-2-pyrid-yl)benzamide.

Gallagher JF, Alley S, Lough AJ - Acta Crystallogr Sect E Struct Rep Online (2010)

Bottom Line: In one mol-ecule, the picoline amide group is directed away from the 2-ferrocenylbenzene moiety (anti) whereas in the other, these are proximate (syn).In the crystal structure, mol-ecules aggregate into dimers via cyclic, asymmetric N-H⋯N inter-actions with graph set R(2) (2)(8), and are further augmented via intra-molecular C-H⋯O=C and inter-dimer C-H⋯π(arene) inter-actions.Dimers are linked into chains along the [102] direction via weak C-H⋯O hydrogen bonds.

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ABSTRACT
The title compound, [Fe(C(5)H(5))(C(18)H(15)N(2)O)], a product of the reaction of 2-ferrocenylbenzoic acid and 2-amino-6-methyl-pyridine, crystallizes with two dissimilar mol-ecules in the asymmetric unit. In one mol-ecule, the picoline amide group is directed away from the 2-ferrocenylbenzene moiety (anti) whereas in the other, these are proximate (syn). In the crystal structure, mol-ecules aggregate into dimers via cyclic, asymmetric N-H⋯N inter-actions with graph set R(2) (2)(8), and are further augmented via intra-molecular C-H⋯O=C and inter-dimer C-H⋯π(arene) inter-actions. Dimers are linked into chains along the [102] direction via weak C-H⋯O hydrogen bonds.

No MeSH data available.


A best fit of molecules (A) and (B) with atoms drawn as their van der Waals spheres.
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Fap4: A best fit of molecules (A) and (B) with atoms drawn as their van der Waals spheres.


2-Ferrocenyl-N-(6-methyl-2-pyrid-yl)benzamide.

Gallagher JF, Alley S, Lough AJ - Acta Crystallogr Sect E Struct Rep Online (2010)

A best fit of molecules (A) and (B) with atoms drawn as their van der Waals spheres.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2983907&req=5

Fap4: A best fit of molecules (A) and (B) with atoms drawn as their van der Waals spheres.
Bottom Line: In one mol-ecule, the picoline amide group is directed away from the 2-ferrocenylbenzene moiety (anti) whereas in the other, these are proximate (syn).In the crystal structure, mol-ecules aggregate into dimers via cyclic, asymmetric N-H⋯N inter-actions with graph set R(2) (2)(8), and are further augmented via intra-molecular C-H⋯O=C and inter-dimer C-H⋯π(arene) inter-actions.Dimers are linked into chains along the [102] direction via weak C-H⋯O hydrogen bonds.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
The title compound, [Fe(C(5)H(5))(C(18)H(15)N(2)O)], a product of the reaction of 2-ferrocenylbenzoic acid and 2-amino-6-methyl-pyridine, crystallizes with two dissimilar mol-ecules in the asymmetric unit. In one mol-ecule, the picoline amide group is directed away from the 2-ferrocenylbenzene moiety (anti) whereas in the other, these are proximate (syn). In the crystal structure, mol-ecules aggregate into dimers via cyclic, asymmetric N-H⋯N inter-actions with graph set R(2) (2)(8), and are further augmented via intra-molecular C-H⋯O=C and inter-dimer C-H⋯π(arene) inter-actions. Dimers are linked into chains along the [102] direction via weak C-H⋯O hydrogen bonds.

No MeSH data available.