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Methoxo[N'-(3-meth-oxy-2-oxidobenzyl-idene)benzohydrazidato]oxidovanadium(V).

Huang SM, Jiang FF, Chen XH, Wu QJ - Acta Crystallogr Sect E Struct Rep Online (2010)

Bottom Line: The V(V) ion is displaced by 0.464 (1) Å from the basal plane towards the axial oxide O atom.Intra-molecular O-H⋯N hydrogen bonding occurs.Inter-molecular C-H⋯O hydrogen bonding is also observed in the crystal structure.

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ABSTRACT
In the title complex, [V(C(15)H(12)N(2)O(4))(CH(3)O)O], the V(V) ion exhibits a distorted square-pyramidal coordination geometry; three donor atoms from a hydrazone ligand and one O atom of the deprotonated methanol define the coordination basal plane. The V(V) ion is displaced by 0.464 (1) Å from the basal plane towards the axial oxide O atom. Intra-molecular O-H⋯N hydrogen bonding occurs. Inter-molecular C-H⋯O hydrogen bonding is also observed in the crystal structure.

No MeSH data available.


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The molecular structure of the title compound, showing 30% probability displacement ellipsoids for non-H atoms. A dashed line indicates the intramoleculat hydrogen bonding.
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Fap1: The molecular structure of the title compound, showing 30% probability displacement ellipsoids for non-H atoms. A dashed line indicates the intramoleculat hydrogen bonding.


Methoxo[N'-(3-meth-oxy-2-oxidobenzyl-idene)benzohydrazidato]oxidovanadium(V).

Huang SM, Jiang FF, Chen XH, Wu QJ - Acta Crystallogr Sect E Struct Rep Online (2010)

The molecular structure of the title compound, showing 30% probability displacement ellipsoids for non-H atoms. A dashed line indicates the intramoleculat hydrogen bonding.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2983900&req=5

Fap1: The molecular structure of the title compound, showing 30% probability displacement ellipsoids for non-H atoms. A dashed line indicates the intramoleculat hydrogen bonding.
Bottom Line: The V(V) ion is displaced by 0.464 (1) Å from the basal plane towards the axial oxide O atom.Intra-molecular O-H⋯N hydrogen bonding occurs.Inter-molecular C-H⋯O hydrogen bonding is also observed in the crystal structure.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the title complex, [V(C(15)H(12)N(2)O(4))(CH(3)O)O], the V(V) ion exhibits a distorted square-pyramidal coordination geometry; three donor atoms from a hydrazone ligand and one O atom of the deprotonated methanol define the coordination basal plane. The V(V) ion is displaced by 0.464 (1) Å from the basal plane towards the axial oxide O atom. Intra-molecular O-H⋯N hydrogen bonding occurs. Inter-molecular C-H⋯O hydrogen bonding is also observed in the crystal structure.

No MeSH data available.


Related in: MedlinePlus