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catena-Poly[[[bis-(2,2'-bipyridine)manganese(II)]-μ(4)-3,3'-sulfanediyldipropionato] bis-(perchlorate)].

Yong L - Acta Crystallogr Sect E Struct Rep Online (2010)

Bottom Line: The title compound, [Mn(2)(C(6)H(8)O(4)S)(C(10)H(8)N(2))(4)](ClO(4))(2), which was crystallized from an aqueous solution, features two Mn(II) atoms in the asymmetric unit, each being coordinated by four N-atom donors from 2,2'-bipyridine ligands and two O atoms of two different 3,3'-sulfanediyldipropionate (L) ligands, with the O atoms in cis positions.The two carboxyl-ate groups of each L ligand, which adopt a syn-anti coordination mode, combine with four Mn(II) atoms, yielding one-dimensional chains extending along [010].

View Article: PubMed Central - HTML - PubMed

Affiliation: Suzhou Vocational University, Suzhou 215104, People's Republic of China.

ABSTRACT
The title compound, [Mn(2)(C(6)H(8)O(4)S)(C(10)H(8)N(2))(4)](ClO(4))(2), which was crystallized from an aqueous solution, features two Mn(II) atoms in the asymmetric unit, each being coordinated by four N-atom donors from 2,2'-bipyridine ligands and two O atoms of two different 3,3'-sulfanediyldipropionate (L) ligands, with the O atoms in cis positions. The two carboxyl-ate groups of each L ligand, which adopt a syn-anti coordination mode, combine with four Mn(II) atoms, yielding one-dimensional chains extending along [010].

No MeSH data available.


The asymmetric unit of the title compound, showing the atom-labelling scheme. For the sake of clarity, hydrogen atoms have been omitted.
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Fap1: The asymmetric unit of the title compound, showing the atom-labelling scheme. For the sake of clarity, hydrogen atoms have been omitted.


catena-Poly[[[bis-(2,2'-bipyridine)manganese(II)]-μ(4)-3,3'-sulfanediyldipropionato] bis-(perchlorate)].

Yong L - Acta Crystallogr Sect E Struct Rep Online (2010)

The asymmetric unit of the title compound, showing the atom-labelling scheme. For the sake of clarity, hydrogen atoms have been omitted.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2983876&req=5

Fap1: The asymmetric unit of the title compound, showing the atom-labelling scheme. For the sake of clarity, hydrogen atoms have been omitted.
Bottom Line: The title compound, [Mn(2)(C(6)H(8)O(4)S)(C(10)H(8)N(2))(4)](ClO(4))(2), which was crystallized from an aqueous solution, features two Mn(II) atoms in the asymmetric unit, each being coordinated by four N-atom donors from 2,2'-bipyridine ligands and two O atoms of two different 3,3'-sulfanediyldipropionate (L) ligands, with the O atoms in cis positions.The two carboxyl-ate groups of each L ligand, which adopt a syn-anti coordination mode, combine with four Mn(II) atoms, yielding one-dimensional chains extending along [010].

View Article: PubMed Central - HTML - PubMed

Affiliation: Suzhou Vocational University, Suzhou 215104, People's Republic of China.

ABSTRACT
The title compound, [Mn(2)(C(6)H(8)O(4)S)(C(10)H(8)N(2))(4)](ClO(4))(2), which was crystallized from an aqueous solution, features two Mn(II) atoms in the asymmetric unit, each being coordinated by four N-atom donors from 2,2'-bipyridine ligands and two O atoms of two different 3,3'-sulfanediyldipropionate (L) ligands, with the O atoms in cis positions. The two carboxyl-ate groups of each L ligand, which adopt a syn-anti coordination mode, combine with four Mn(II) atoms, yielding one-dimensional chains extending along [010].

No MeSH data available.