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Poly[tetra-aqua-(μ(4)-benzene-1,3,5-tri-carboxyl-ato)sodium(I)zinc(II)].

Ma CH, Wang XY, Dong XW, Li YJ - Acta Crystallogr Sect E Struct Rep Online (2010)

Bottom Line: In the title compound, [NaZn(C(9)H(3)O(6))(H(2)O)(4)](n), the Zn(II) atom is six-coordinated by four O atoms from two different benzene-1,3,5-tricarboxyl-ate anions and two water O atoms in a distorted tetragonal-bipyramidal geometry and the Na(I) atom is five-coordinated by three O atoms from three different benzene-1,3,5-tricarboxyl-ate anions and two water O atoms in a distorted trigonal-bipyramidal geometry.The benzene-1,3,5-tricarboxyl-ate anion bridges two Zn(II) atoms and two Na(I) atoms, resulting in the formation of a two-dimensional layer structure.Inter-molecular O-H⋯O hydrogen-bonding inter-actions generate a three-dimensional superamolecular structure.

View Article: PubMed Central - HTML - PubMed

Affiliation: Jilin Agricultural Science and Technology College, Jilin 132101, People's Republic of China.

ABSTRACT
In the title compound, [NaZn(C(9)H(3)O(6))(H(2)O)(4)](n), the Zn(II) atom is six-coordinated by four O atoms from two different benzene-1,3,5-tricarboxyl-ate anions and two water O atoms in a distorted tetragonal-bipyramidal geometry and the Na(I) atom is five-coordinated by three O atoms from three different benzene-1,3,5-tricarboxyl-ate anions and two water O atoms in a distorted trigonal-bipyramidal geometry. The benzene-1,3,5-tricarboxyl-ate anion bridges two Zn(II) atoms and two Na(I) atoms, resulting in the formation of a two-dimensional layer structure. Inter-molecular O-H⋯O hydrogen-bonding inter-actions generate a three-dimensional superamolecular structure.

No MeSH data available.


ORTEP diagram of the coordination environments for ZnII atom and NaI atom in (I), showing 30% probability displacement ellipsoids, crystalline water molecules and the atomic numbering scheme [symmetry code: (i) 1-x, y, 1.5-z; (ii) x-0.5, 1.5-y, z-0.5; (iii) x, y-1, z]. H atoms have been omitted for clarity.
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Fap1: ORTEP diagram of the coordination environments for ZnII atom and NaI atom in (I), showing 30% probability displacement ellipsoids, crystalline water molecules and the atomic numbering scheme [symmetry code: (i) 1-x, y, 1.5-z; (ii) x-0.5, 1.5-y, z-0.5; (iii) x, y-1, z]. H atoms have been omitted for clarity.


Poly[tetra-aqua-(μ(4)-benzene-1,3,5-tri-carboxyl-ato)sodium(I)zinc(II)].

Ma CH, Wang XY, Dong XW, Li YJ - Acta Crystallogr Sect E Struct Rep Online (2010)

ORTEP diagram of the coordination environments for ZnII atom and NaI atom in (I), showing 30% probability displacement ellipsoids, crystalline water molecules and the atomic numbering scheme [symmetry code: (i) 1-x, y, 1.5-z; (ii) x-0.5, 1.5-y, z-0.5; (iii) x, y-1, z]. H atoms have been omitted for clarity.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2983871&req=5

Fap1: ORTEP diagram of the coordination environments for ZnII atom and NaI atom in (I), showing 30% probability displacement ellipsoids, crystalline water molecules and the atomic numbering scheme [symmetry code: (i) 1-x, y, 1.5-z; (ii) x-0.5, 1.5-y, z-0.5; (iii) x, y-1, z]. H atoms have been omitted for clarity.
Bottom Line: In the title compound, [NaZn(C(9)H(3)O(6))(H(2)O)(4)](n), the Zn(II) atom is six-coordinated by four O atoms from two different benzene-1,3,5-tricarboxyl-ate anions and two water O atoms in a distorted tetragonal-bipyramidal geometry and the Na(I) atom is five-coordinated by three O atoms from three different benzene-1,3,5-tricarboxyl-ate anions and two water O atoms in a distorted trigonal-bipyramidal geometry.The benzene-1,3,5-tricarboxyl-ate anion bridges two Zn(II) atoms and two Na(I) atoms, resulting in the formation of a two-dimensional layer structure.Inter-molecular O-H⋯O hydrogen-bonding inter-actions generate a three-dimensional superamolecular structure.

View Article: PubMed Central - HTML - PubMed

Affiliation: Jilin Agricultural Science and Technology College, Jilin 132101, People's Republic of China.

ABSTRACT
In the title compound, [NaZn(C(9)H(3)O(6))(H(2)O)(4)](n), the Zn(II) atom is six-coordinated by four O atoms from two different benzene-1,3,5-tricarboxyl-ate anions and two water O atoms in a distorted tetragonal-bipyramidal geometry and the Na(I) atom is five-coordinated by three O atoms from three different benzene-1,3,5-tricarboxyl-ate anions and two water O atoms in a distorted trigonal-bipyramidal geometry. The benzene-1,3,5-tricarboxyl-ate anion bridges two Zn(II) atoms and two Na(I) atoms, resulting in the formation of a two-dimensional layer structure. Inter-molecular O-H⋯O hydrogen-bonding inter-actions generate a three-dimensional superamolecular structure.

No MeSH data available.