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catena-Poly[sodium-di-μ-aqua-sodium-bis[μ-2,2,2-trichloro-N-(dimorpholinophosphoryl)acetamide]].

Litsis OO, Ovchynnikov VA, Sliva TY, Konovalova IS, Amirkhanov VM - Acta Crystallogr Sect E Struct Rep Online (2010)

Bottom Line: The Na(I) ion is five-coordinated in a distorted trigonal-bipyramidal geometry.A bridging coordination of the CAPh ligand via the carbonyl O atom is observed for the first time.The bridging water mol-ecules form inter-molecular O-H⋯O hydrogen bonds with the O atoms of the morpholine rings and the phosphoryl groups of neighboring CAPh mol-ecules.

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ABSTRACT
The title compound, [Na(2)(C(10)H(16)Cl(3)N(3)O(4)P)(2)(H(2)O)(2)](n), can be considered as a two-dimensional coordination polymer in which one-dimensional chains are connected to each other by inter-molecular C-H⋯O hydrogen bonds involving the water mol-ecules. The Na(I) ion is five-coordinated in a distorted trigonal-bipyramidal geometry. The connection between the two Na(I) ions is facilitated by the two μ-O atoms of the carbonyl group of the 2,2,2-trichloro-N-(dimorpholino-phosphor-yl)acetamide (CAPh) ligand. A bridging coordination of the CAPh ligand via the carbonyl O atom is observed for the first time. The bridging water mol-ecules form inter-molecular O-H⋯O hydrogen bonds with the O atoms of the morpholine rings and the phosphoryl groups of neighboring CAPh mol-ecules.

No MeSH data available.


A portion of polymeric chain of the title compound, showing the 30% probability displacement ellipsoids and atomic numbering [symmetry codes: ]. H atoms of L- and Cl atoms of trychlormethyl groups have been omitted for clarity.
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Fap1: A portion of polymeric chain of the title compound, showing the 30% probability displacement ellipsoids and atomic numbering [symmetry codes: ]. H atoms of L- and Cl atoms of trychlormethyl groups have been omitted for clarity.


catena-Poly[sodium-di-μ-aqua-sodium-bis[μ-2,2,2-trichloro-N-(dimorpholinophosphoryl)acetamide]].

Litsis OO, Ovchynnikov VA, Sliva TY, Konovalova IS, Amirkhanov VM - Acta Crystallogr Sect E Struct Rep Online (2010)

A portion of polymeric chain of the title compound, showing the 30% probability displacement ellipsoids and atomic numbering [symmetry codes: ]. H atoms of L- and Cl atoms of trychlormethyl groups have been omitted for clarity.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2983831&req=5

Fap1: A portion of polymeric chain of the title compound, showing the 30% probability displacement ellipsoids and atomic numbering [symmetry codes: ]. H atoms of L- and Cl atoms of trychlormethyl groups have been omitted for clarity.
Bottom Line: The Na(I) ion is five-coordinated in a distorted trigonal-bipyramidal geometry.A bridging coordination of the CAPh ligand via the carbonyl O atom is observed for the first time.The bridging water mol-ecules form inter-molecular O-H⋯O hydrogen bonds with the O atoms of the morpholine rings and the phosphoryl groups of neighboring CAPh mol-ecules.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
The title compound, [Na(2)(C(10)H(16)Cl(3)N(3)O(4)P)(2)(H(2)O)(2)](n), can be considered as a two-dimensional coordination polymer in which one-dimensional chains are connected to each other by inter-molecular C-H⋯O hydrogen bonds involving the water mol-ecules. The Na(I) ion is five-coordinated in a distorted trigonal-bipyramidal geometry. The connection between the two Na(I) ions is facilitated by the two μ-O atoms of the carbonyl group of the 2,2,2-trichloro-N-(dimorpholino-phosphor-yl)acetamide (CAPh) ligand. A bridging coordination of the CAPh ligand via the carbonyl O atom is observed for the first time. The bridging water mol-ecules form inter-molecular O-H⋯O hydrogen bonds with the O atoms of the morpholine rings and the phosphoryl groups of neighboring CAPh mol-ecules.

No MeSH data available.