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Poly[(dimethyl-formamide)(μ(4)-2,2'-sulfanediyldibenzoato)nickel(II)].

Xie JB - Acta Crystallogr Sect E Struct Rep Online (2010)

Bottom Line: The title centrosymmetric dinuclear Ni(II) complex, [Ni(C(14)H(8)O(4)S)(C(3)H(7)NO)](n), was prepared via reaction of Ni(NO(3))(2)·6H(2)O and thio-salicylic acid, with H(2)O and dimethyl-formamide (DMF) as the mixed solvent.The central Ni(II) ion is five-coordinated by five O atoms from DMF and from the carboxyl-ate groups of the organic ligand.The symmetry-related coordination polyhedra inter-link into centrosymmetric dimeric units and these, in turn, are linked into infinite chains propagating parallel to [100].

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Affiliation: College of Materials Science and Engineering, North University of China, Taiyuan, Shanxi, 030051, People's Republic of China.

ABSTRACT
The title centrosymmetric dinuclear Ni(II) complex, [Ni(C(14)H(8)O(4)S)(C(3)H(7)NO)](n), was prepared via reaction of Ni(NO(3))(2)·6H(2)O and thio-salicylic acid, with H(2)O and dimethyl-formamide (DMF) as the mixed solvent. The central Ni(II) ion is five-coordinated by five O atoms from DMF and from the carboxyl-ate groups of the organic ligand. The symmetry-related coordination polyhedra inter-link into centrosymmetric dimeric units and these, in turn, are linked into infinite chains propagating parallel to [100].

No MeSH data available.


The packing diagram of the title compound (I).
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Fap2: The packing diagram of the title compound (I).


Poly[(dimethyl-formamide)(μ(4)-2,2'-sulfanediyldibenzoato)nickel(II)].

Xie JB - Acta Crystallogr Sect E Struct Rep Online (2010)

The packing diagram of the title compound (I).
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2983770&req=5

Fap2: The packing diagram of the title compound (I).
Bottom Line: The title centrosymmetric dinuclear Ni(II) complex, [Ni(C(14)H(8)O(4)S)(C(3)H(7)NO)](n), was prepared via reaction of Ni(NO(3))(2)·6H(2)O and thio-salicylic acid, with H(2)O and dimethyl-formamide (DMF) as the mixed solvent.The central Ni(II) ion is five-coordinated by five O atoms from DMF and from the carboxyl-ate groups of the organic ligand.The symmetry-related coordination polyhedra inter-link into centrosymmetric dimeric units and these, in turn, are linked into infinite chains propagating parallel to [100].

View Article: PubMed Central - HTML - PubMed

Affiliation: College of Materials Science and Engineering, North University of China, Taiyuan, Shanxi, 030051, People's Republic of China.

ABSTRACT
The title centrosymmetric dinuclear Ni(II) complex, [Ni(C(14)H(8)O(4)S)(C(3)H(7)NO)](n), was prepared via reaction of Ni(NO(3))(2)·6H(2)O and thio-salicylic acid, with H(2)O and dimethyl-formamide (DMF) as the mixed solvent. The central Ni(II) ion is five-coordinated by five O atoms from DMF and from the carboxyl-ate groups of the organic ligand. The symmetry-related coordination polyhedra inter-link into centrosymmetric dimeric units and these, in turn, are linked into infinite chains propagating parallel to [100].

No MeSH data available.