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[(Z)-O-Isopropyl N-(m-tol-yl)thio-carbamato-κS](tricyclo-hexyl-phosphine-κP)gold(I).

Tadbuppa PP, Tiekink ER - Acta Crystallogr Sect E Struct Rep Online (2010)

Bottom Line: The Au atom in the title compound, [Au(C(11)H(14)NOS)(C(18)H(33)P)], is coordinated within an S,P-donor set that defines a slightly distorted linear geometry [S-Au-P = 174.73 (3)°], with the distortion due in part to a close intra-molecular Au⋯O contact [3.060 (3) Å].In the crystal structure, mol-ecules are arranged in layers in the bc plane with the primary connections between the arrays being of the type C-H⋯π.

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ABSTRACT
The Au atom in the title compound, [Au(C(11)H(14)NOS)(C(18)H(33)P)], is coordinated within an S,P-donor set that defines a slightly distorted linear geometry [S-Au-P = 174.73 (3)°], with the distortion due in part to a close intra-molecular Au⋯O contact [3.060 (3) Å]. In the crystal structure, mol-ecules are arranged in layers in the bc plane with the primary connections between the arrays being of the type C-H⋯π.

No MeSH data available.


Related in: MedlinePlus

A view of the unit cell contents of (I) shown in projection down the b axis with the C–H···π interactions shown as purple dashed lines. Colour code: Au, orange; S, yellow; P, pink; O, red; N, blue; C, grey; and H, green.
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Fap2: A view of the unit cell contents of (I) shown in projection down the b axis with the C–H···π interactions shown as purple dashed lines. Colour code: Au, orange; S, yellow; P, pink; O, red; N, blue; C, grey; and H, green.


[(Z)-O-Isopropyl N-(m-tol-yl)thio-carbamato-κS](tricyclo-hexyl-phosphine-κP)gold(I).

Tadbuppa PP, Tiekink ER - Acta Crystallogr Sect E Struct Rep Online (2010)

A view of the unit cell contents of (I) shown in projection down the b axis with the C–H···π interactions shown as purple dashed lines. Colour code: Au, orange; S, yellow; P, pink; O, red; N, blue; C, grey; and H, green.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2983763&req=5

Fap2: A view of the unit cell contents of (I) shown in projection down the b axis with the C–H···π interactions shown as purple dashed lines. Colour code: Au, orange; S, yellow; P, pink; O, red; N, blue; C, grey; and H, green.
Bottom Line: The Au atom in the title compound, [Au(C(11)H(14)NOS)(C(18)H(33)P)], is coordinated within an S,P-donor set that defines a slightly distorted linear geometry [S-Au-P = 174.73 (3)°], with the distortion due in part to a close intra-molecular Au⋯O contact [3.060 (3) Å].In the crystal structure, mol-ecules are arranged in layers in the bc plane with the primary connections between the arrays being of the type C-H⋯π.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
The Au atom in the title compound, [Au(C(11)H(14)NOS)(C(18)H(33)P)], is coordinated within an S,P-donor set that defines a slightly distorted linear geometry [S-Au-P = 174.73 (3)°], with the distortion due in part to a close intra-molecular Au⋯O contact [3.060 (3) Å]. In the crystal structure, mol-ecules are arranged in layers in the bc plane with the primary connections between the arrays being of the type C-H⋯π.

No MeSH data available.


Related in: MedlinePlus