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fac-(2-Amido-ethyl-κC,O)aqua-tri-chlorido-tin(IV) 1,4,7,10,13,16-hexa-oxacyclo-octa-decane (2/1).

Wardell SM, Harrison WT, Tiekink ER, de Lima GM, Wardell JL - Acta Crystallogr Sect E Struct Rep Online (2010)

Bottom Line: The resulting CCl(3)O(2) donor set defines a distorted octa-hedral geometry.The tin-bound aqua ligand forms O-H⋯O hydrogen bonds to the centrosymmetric 18-crown-6 mol-ecule, resulting in a tri-mol-ecular aggregate.These assemble into a supra-molecular chain along the a axis being connected by N-H⋯O hydrogen bonds.

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ABSTRACT
The asymmetric unit of the title compound, [Sn(C(3)H(6)NO)Cl(3)(H(2)O)](2)·C(12)H(24)O(6), comprises a six-coordinate tin complex and a 18-crown-6 mol-ecule, the latter disposed about a centre of inversion. The tin atom is coordinated by three Cl atoms, that define a facial arrangement, a chelating C-,O- ligand, and a water mol-ecule. The resulting CCl(3)O(2) donor set defines a distorted octa-hedral geometry. The tin-bound aqua ligand forms O-H⋯O hydrogen bonds to the centrosymmetric 18-crown-6 mol-ecule, resulting in a tri-mol-ecular aggregate. These assemble into a supra-molecular chain along the a axis being connected by N-H⋯O hydrogen bonds.

No MeSH data available.


Related in: MedlinePlus

The molecular structure of a tri-molecular aggregate in (I) showing the atom-labelling scheme and displacement ellipsoids at the 50% probability level. Dashed lines indicate hydrogen bonds.
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Fap1: The molecular structure of a tri-molecular aggregate in (I) showing the atom-labelling scheme and displacement ellipsoids at the 50% probability level. Dashed lines indicate hydrogen bonds.


fac-(2-Amido-ethyl-κC,O)aqua-tri-chlorido-tin(IV) 1,4,7,10,13,16-hexa-oxacyclo-octa-decane (2/1).

Wardell SM, Harrison WT, Tiekink ER, de Lima GM, Wardell JL - Acta Crystallogr Sect E Struct Rep Online (2010)

The molecular structure of a tri-molecular aggregate in (I) showing the atom-labelling scheme and displacement ellipsoids at the 50% probability level. Dashed lines indicate hydrogen bonds.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2983741&req=5

Fap1: The molecular structure of a tri-molecular aggregate in (I) showing the atom-labelling scheme and displacement ellipsoids at the 50% probability level. Dashed lines indicate hydrogen bonds.
Bottom Line: The resulting CCl(3)O(2) donor set defines a distorted octa-hedral geometry.The tin-bound aqua ligand forms O-H⋯O hydrogen bonds to the centrosymmetric 18-crown-6 mol-ecule, resulting in a tri-mol-ecular aggregate.These assemble into a supra-molecular chain along the a axis being connected by N-H⋯O hydrogen bonds.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
The asymmetric unit of the title compound, [Sn(C(3)H(6)NO)Cl(3)(H(2)O)](2)·C(12)H(24)O(6), comprises a six-coordinate tin complex and a 18-crown-6 mol-ecule, the latter disposed about a centre of inversion. The tin atom is coordinated by three Cl atoms, that define a facial arrangement, a chelating C-,O- ligand, and a water mol-ecule. The resulting CCl(3)O(2) donor set defines a distorted octa-hedral geometry. The tin-bound aqua ligand forms O-H⋯O hydrogen bonds to the centrosymmetric 18-crown-6 mol-ecule, resulting in a tri-mol-ecular aggregate. These assemble into a supra-molecular chain along the a axis being connected by N-H⋯O hydrogen bonds.

No MeSH data available.


Related in: MedlinePlus