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Tetra-kis(μ-3,4-dimethoxy-phenyl-acetato)bis-[(3,4-dimethoxy-phenyl-acetato)(1,10-phenanthroline)dysprosium(III)].

Liu JF, Xu XD, Li HQ, Zhao GL - Acta Crystallogr Sect E Struct Rep Online (2010)

Bottom Line: The Dy(III) atom is nine-coordinated by seven O atoms from five L ligands and two N atoms from the phen mol-ecules.The L ligands are coordinated to the Dy(III) ion in three coordination modes: chelating, bridging and bridging-tridentate.C-H⋯O hydrogen bonding interactions consolidate the crystal packing.

View Article: PubMed Central - HTML - PubMed

Affiliation: Zhejiang Key Laboratory for Reactive Chemistry on Solid Surfaces, Institute of Physical Chemistry, Zhejiang Normal University, Jinhua, Zhejiang 321004, People's Republic of China, and College of Chemistry and Life Science, Zhejiang Normal University, Jinhua 321004, Zhejiang, People's Republic of China.

ABSTRACT
The title centrosymmetric dinuclear dysprosium(III) complex, [Dy(2)(C(10)H(11)O(4))(6)(C(12)H(8)N(2))(2)] or [Dy(L)(3)phen](2), is comprised of six 3,4-dimethoxy-phenylacetate (L) anions, two 1,10-phenanthroline (phen) mol-ecules and two Dy(III) ions. The Dy(III) atom is nine-coordinated by seven O atoms from five L ligands and two N atoms from the phen mol-ecules. The L ligands are coordinated to the Dy(III) ion in three coordination modes: chelating, bridging and bridging-tridentate. C-H⋯O hydrogen bonding interactions consolidate the crystal packing.

No MeSH data available.


The molecular structure of the title complex. Displacement ellipsoids are drawn at the 30% probability level. The letter A in the atomic labels represents the symmetry operation: -x, -y+1, -z+1.
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Fap1: The molecular structure of the title complex. Displacement ellipsoids are drawn at the 30% probability level. The letter A in the atomic labels represents the symmetry operation: -x, -y+1, -z+1.


Tetra-kis(μ-3,4-dimethoxy-phenyl-acetato)bis-[(3,4-dimethoxy-phenyl-acetato)(1,10-phenanthroline)dysprosium(III)].

Liu JF, Xu XD, Li HQ, Zhao GL - Acta Crystallogr Sect E Struct Rep Online (2010)

The molecular structure of the title complex. Displacement ellipsoids are drawn at the 30% probability level. The letter A in the atomic labels represents the symmetry operation: -x, -y+1, -z+1.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2983715&req=5

Fap1: The molecular structure of the title complex. Displacement ellipsoids are drawn at the 30% probability level. The letter A in the atomic labels represents the symmetry operation: -x, -y+1, -z+1.
Bottom Line: The Dy(III) atom is nine-coordinated by seven O atoms from five L ligands and two N atoms from the phen mol-ecules.The L ligands are coordinated to the Dy(III) ion in three coordination modes: chelating, bridging and bridging-tridentate.C-H⋯O hydrogen bonding interactions consolidate the crystal packing.

View Article: PubMed Central - HTML - PubMed

Affiliation: Zhejiang Key Laboratory for Reactive Chemistry on Solid Surfaces, Institute of Physical Chemistry, Zhejiang Normal University, Jinhua, Zhejiang 321004, People's Republic of China, and College of Chemistry and Life Science, Zhejiang Normal University, Jinhua 321004, Zhejiang, People's Republic of China.

ABSTRACT
The title centrosymmetric dinuclear dysprosium(III) complex, [Dy(2)(C(10)H(11)O(4))(6)(C(12)H(8)N(2))(2)] or [Dy(L)(3)phen](2), is comprised of six 3,4-dimethoxy-phenylacetate (L) anions, two 1,10-phenanthroline (phen) mol-ecules and two Dy(III) ions. The Dy(III) atom is nine-coordinated by seven O atoms from five L ligands and two N atoms from the phen mol-ecules. The L ligands are coordinated to the Dy(III) ion in three coordination modes: chelating, bridging and bridging-tridentate. C-H⋯O hydrogen bonding interactions consolidate the crystal packing.

No MeSH data available.