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Ethyl [1-(4-bromo-phen-yl)-1-hydr-oxy-3-oxobut-yl](phen-yl)phosphinate monohydrate.

Samanta S, Perera S, Broker GA, Zhao CG, Tiekink ER - Acta Crystallogr Sect E Struct Rep Online (2010)

Bottom Line: In the title hydrate, C(18)H(20)BrO(4)P·H(2)O, a staggered conformation is found when the organic mol-ecule is viewed down the central P-C bond, with the oxo and hydroxyl groups being diagonally opposite; each of the central P and C atoms has an S-configuration.The crystal structure features supra-molecular double chains along the b axis mediated by O(hydrox-yl)-H⋯O(oxo), O(water)-H⋯O(oxo), and O(water)-H⋯O(water) hydrogen bonds.

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ABSTRACT
In the title hydrate, C(18)H(20)BrO(4)P·H(2)O, a staggered conformation is found when the organic mol-ecule is viewed down the central P-C bond, with the oxo and hydroxyl groups being diagonally opposite; each of the central P and C atoms has an S-configuration. The crystal structure features supra-molecular double chains along the b axis mediated by O(hydrox-yl)-H⋯O(oxo), O(water)-H⋯O(oxo), and O(water)-H⋯O(water) hydrogen bonds.

No MeSH data available.


Supramolecular double chain along the b axis in (I) mediated by O–H···O hydrogen bonding (orange dashed lines). Colour scheme: Br, olive; P. pink; O, red; N, blue; C, grey; and H, green.
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Fap2: Supramolecular double chain along the b axis in (I) mediated by O–H···O hydrogen bonding (orange dashed lines). Colour scheme: Br, olive; P. pink; O, red; N, blue; C, grey; and H, green.


Ethyl [1-(4-bromo-phen-yl)-1-hydr-oxy-3-oxobut-yl](phen-yl)phosphinate monohydrate.

Samanta S, Perera S, Broker GA, Zhao CG, Tiekink ER - Acta Crystallogr Sect E Struct Rep Online (2010)

Supramolecular double chain along the b axis in (I) mediated by O–H···O hydrogen bonding (orange dashed lines). Colour scheme: Br, olive; P. pink; O, red; N, blue; C, grey; and H, green.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2983684&req=5

Fap2: Supramolecular double chain along the b axis in (I) mediated by O–H···O hydrogen bonding (orange dashed lines). Colour scheme: Br, olive; P. pink; O, red; N, blue; C, grey; and H, green.
Bottom Line: In the title hydrate, C(18)H(20)BrO(4)P·H(2)O, a staggered conformation is found when the organic mol-ecule is viewed down the central P-C bond, with the oxo and hydroxyl groups being diagonally opposite; each of the central P and C atoms has an S-configuration.The crystal structure features supra-molecular double chains along the b axis mediated by O(hydrox-yl)-H⋯O(oxo), O(water)-H⋯O(oxo), and O(water)-H⋯O(water) hydrogen bonds.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the title hydrate, C(18)H(20)BrO(4)P·H(2)O, a staggered conformation is found when the organic mol-ecule is viewed down the central P-C bond, with the oxo and hydroxyl groups being diagonally opposite; each of the central P and C atoms has an S-configuration. The crystal structure features supra-molecular double chains along the b axis mediated by O(hydrox-yl)-H⋯O(oxo), O(water)-H⋯O(oxo), and O(water)-H⋯O(water) hydrogen bonds.

No MeSH data available.