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4-(4-Chloro-phen-yl)piperidin-4-ol.

Dutkiewicz G, Siddaraju BP, Yathirajan HS, Siddegowda MS, Kubicki M - Acta Crystallogr Sect E Struct Rep Online (2010)

Bottom Line: In the title compound, C(11)H(14)ClNO, the piperidine ring adopts a chair conformation: the hydroxyl substituent and the N-bound H atom occupy the axial positions, while the benzene ring occupies the equatorial position.In the crystal, the mol-ecules are linked into a centrosymmetric tetra-mer through strong O-H⋯N and weak N-H⋯O hydrogen bonds; the N and O atoms act as both donor and acceptor for these inter-actions.The tetra-mers are further joined by hydrogen bonds into a layer parallel to (100).

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ABSTRACT
In the title compound, C(11)H(14)ClNO, the piperidine ring adopts a chair conformation: the hydroxyl substituent and the N-bound H atom occupy the axial positions, while the benzene ring occupies the equatorial position. In the crystal, the mol-ecules are linked into a centrosymmetric tetra-mer through strong O-H⋯N and weak N-H⋯O hydrogen bonds; the N and O atoms act as both donor and acceptor for these inter-actions. The tetra-mers are further joined by hydrogen bonds into a layer parallel to (100).

No MeSH data available.


Hydrogen-bonded tetramer [symmetry codes: (i) x, 1/2 - y, 1/2 + z; (ii) 2 - x, 1 - y, 1 - z; (iii) 2 - x, 1/2 + y, 1/2 - z].
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Fap2: Hydrogen-bonded tetramer [symmetry codes: (i) x, 1/2 - y, 1/2 + z; (ii) 2 - x, 1 - y, 1 - z; (iii) 2 - x, 1/2 + y, 1/2 - z].


4-(4-Chloro-phen-yl)piperidin-4-ol.

Dutkiewicz G, Siddaraju BP, Yathirajan HS, Siddegowda MS, Kubicki M - Acta Crystallogr Sect E Struct Rep Online (2010)

Hydrogen-bonded tetramer [symmetry codes: (i) x, 1/2 - y, 1/2 + z; (ii) 2 - x, 1 - y, 1 - z; (iii) 2 - x, 1/2 + y, 1/2 - z].
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2983646&req=5

Fap2: Hydrogen-bonded tetramer [symmetry codes: (i) x, 1/2 - y, 1/2 + z; (ii) 2 - x, 1 - y, 1 - z; (iii) 2 - x, 1/2 + y, 1/2 - z].
Bottom Line: In the title compound, C(11)H(14)ClNO, the piperidine ring adopts a chair conformation: the hydroxyl substituent and the N-bound H atom occupy the axial positions, while the benzene ring occupies the equatorial position.In the crystal, the mol-ecules are linked into a centrosymmetric tetra-mer through strong O-H⋯N and weak N-H⋯O hydrogen bonds; the N and O atoms act as both donor and acceptor for these inter-actions.The tetra-mers are further joined by hydrogen bonds into a layer parallel to (100).

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the title compound, C(11)H(14)ClNO, the piperidine ring adopts a chair conformation: the hydroxyl substituent and the N-bound H atom occupy the axial positions, while the benzene ring occupies the equatorial position. In the crystal, the mol-ecules are linked into a centrosymmetric tetra-mer through strong O-H⋯N and weak N-H⋯O hydrogen bonds; the N and O atoms act as both donor and acceptor for these inter-actions. The tetra-mers are further joined by hydrogen bonds into a layer parallel to (100).

No MeSH data available.