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{1,5,9-Tris[(2S)-2-hydroxy-prop-yl]-1,5,9-triaza-cyclo-dodeca-ne}zinc(II) dinitrate monohydrate.

Strasser CE, Sumani JE, Raubenheimer HG, Luckay RC - Acta Crystallogr Sect E Struct Rep Online (2010)

Bottom Line: In the title compound, [Zn(C(18)H(39)N(3)O(3))](NO(3))(2)·H(2)O, the coordination geometry around the central Zn(II) atom is distorted octa-hedral.The hydroxyl groups in the macrocyclic ligand and water mol-ecules are engaged in O-H⋯O hydrogen bonding, which forms two-dimensional corrugated sheets comprising 34-membered rings.Neighbouring sheets are connected by C-H⋯O inter-actions.

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Affiliation: Department of Chemistry and Polymer Science, University of Stellenbosch, Private Bag X1, Matieland, 7602, South Africa.

ABSTRACT
In the title compound, [Zn(C(18)H(39)N(3)O(3))](NO(3))(2)·H(2)O, the coordination geometry around the central Zn(II) atom is distorted octa-hedral. The hydroxyl groups in the macrocyclic ligand and water mol-ecules are engaged in O-H⋯O hydrogen bonding, which forms two-dimensional corrugated sheets comprising 34-membered rings. Neighbouring sheets are connected by C-H⋯O inter-actions.

No MeSH data available.


Part of the infinite sheet formed by hydrogen bonds (dashed lines).
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Fap2: Part of the infinite sheet formed by hydrogen bonds (dashed lines).


{1,5,9-Tris[(2S)-2-hydroxy-prop-yl]-1,5,9-triaza-cyclo-dodeca-ne}zinc(II) dinitrate monohydrate.

Strasser CE, Sumani JE, Raubenheimer HG, Luckay RC - Acta Crystallogr Sect E Struct Rep Online (2010)

Part of the infinite sheet formed by hydrogen bonds (dashed lines).
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2983634&req=5

Fap2: Part of the infinite sheet formed by hydrogen bonds (dashed lines).
Bottom Line: In the title compound, [Zn(C(18)H(39)N(3)O(3))](NO(3))(2)·H(2)O, the coordination geometry around the central Zn(II) atom is distorted octa-hedral.The hydroxyl groups in the macrocyclic ligand and water mol-ecules are engaged in O-H⋯O hydrogen bonding, which forms two-dimensional corrugated sheets comprising 34-membered rings.Neighbouring sheets are connected by C-H⋯O inter-actions.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry and Polymer Science, University of Stellenbosch, Private Bag X1, Matieland, 7602, South Africa.

ABSTRACT
In the title compound, [Zn(C(18)H(39)N(3)O(3))](NO(3))(2)·H(2)O, the coordination geometry around the central Zn(II) atom is distorted octa-hedral. The hydroxyl groups in the macrocyclic ligand and water mol-ecules are engaged in O-H⋯O hydrogen bonding, which forms two-dimensional corrugated sheets comprising 34-membered rings. Neighbouring sheets are connected by C-H⋯O inter-actions.

No MeSH data available.