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μ-Succinato-bis-[aqua-(2,2':6',2''-terpyridine)copper(II)] dinitrate dihydrate.

Mei C, Lei Q, Zhang P - Acta Crystallogr Sect E Struct Rep Online (2010)

Bottom Line: The title compound, [Cu(2)(C(4)H(4)O(4))(C(15)H(11)N(3))(2)(H(2)O)(2)](NO(3))(2)·2H(2)O, was synthesized under hydro-thermal conditions.The Cu(II) ion is penta-coordinated in a tetra-gonal-pyramidal geometry, with one O atom of a succinate dianion and three N atoms of a 2,2':6',2''-terpyridine ligand occupying the basal plane, and a water O atom located at the apical site.In the crystal structure, O-H⋯O hydrogen bonding links the mol-ecules into a chain parallel to the a axis.

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Affiliation: Institute of Environmental and Municipal Engineering, North China University of Water Conservancy and Electric Power, Zhengzhou 450011, People's Republic of China.

ABSTRACT
The title compound, [Cu(2)(C(4)H(4)O(4))(C(15)H(11)N(3))(2)(H(2)O)(2)](NO(3))(2)·2H(2)O, was synthesized under hydro-thermal conditions. The dinuclear copper complex is located on a crystallographic inversion centre. The Cu(II) ion is penta-coordinated in a tetra-gonal-pyramidal geometry, with one O atom of a succinate dianion and three N atoms of a 2,2':6',2''-terpyridine ligand occupying the basal plane, and a water O atom located at the apical site. In the crystal structure, O-H⋯O hydrogen bonding links the mol-ecules into a chain parallel to the a axis.

No MeSH data available.


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Crystal packing of the title complound. Hydrogen-bond interactions are drawn with dashed lines.
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Fap2: Crystal packing of the title complound. Hydrogen-bond interactions are drawn with dashed lines.


μ-Succinato-bis-[aqua-(2,2':6',2''-terpyridine)copper(II)] dinitrate dihydrate.

Mei C, Lei Q, Zhang P - Acta Crystallogr Sect E Struct Rep Online (2010)

Crystal packing of the title complound. Hydrogen-bond interactions are drawn with dashed lines.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2983631&req=5

Fap2: Crystal packing of the title complound. Hydrogen-bond interactions are drawn with dashed lines.
Bottom Line: The title compound, [Cu(2)(C(4)H(4)O(4))(C(15)H(11)N(3))(2)(H(2)O)(2)](NO(3))(2)·2H(2)O, was synthesized under hydro-thermal conditions.The Cu(II) ion is penta-coordinated in a tetra-gonal-pyramidal geometry, with one O atom of a succinate dianion and three N atoms of a 2,2':6',2''-terpyridine ligand occupying the basal plane, and a water O atom located at the apical site.In the crystal structure, O-H⋯O hydrogen bonding links the mol-ecules into a chain parallel to the a axis.

View Article: PubMed Central - HTML - PubMed

Affiliation: Institute of Environmental and Municipal Engineering, North China University of Water Conservancy and Electric Power, Zhengzhou 450011, People's Republic of China.

ABSTRACT
The title compound, [Cu(2)(C(4)H(4)O(4))(C(15)H(11)N(3))(2)(H(2)O)(2)](NO(3))(2)·2H(2)O, was synthesized under hydro-thermal conditions. The dinuclear copper complex is located on a crystallographic inversion centre. The Cu(II) ion is penta-coordinated in a tetra-gonal-pyramidal geometry, with one O atom of a succinate dianion and three N atoms of a 2,2':6',2''-terpyridine ligand occupying the basal plane, and a water O atom located at the apical site. In the crystal structure, O-H⋯O hydrogen bonding links the mol-ecules into a chain parallel to the a axis.

No MeSH data available.


Related in: MedlinePlus