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(8-Bromo-2-hydroxy-7-methoxy-1-naph-thyl)(4-chlorobenzoyl)methanone.

Mitsui R, Nakaema K, Nagasawa A, Noguchi K, Yonezawa N - Acta Crystallogr Sect E Struct Rep Online (2010)

Bottom Line: In the title compound, C(18)H(12)BrClO(3), the naphthalene ring system and the benzene ring make a dihedral angle of 82.18 (9)°.The conformation around the central C=O group is such that the C=O bond vector forms a larger angle to the plane of the naphthalene ring system than to the plane of the benzene ring, viz. 60.91 (16)° versus 13.94 (16)°.In the crystal structure, two π-π inter-actions formed between the naphthalene ring systems [centroid-centroid distances of 3.8014 (13) and 3.9823 (13) Å] and inter-molecular O-H⋯O and C-H⋯O hydrogen bonds are present.

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ABSTRACT
In the title compound, C(18)H(12)BrClO(3), the naphthalene ring system and the benzene ring make a dihedral angle of 82.18 (9)°. The conformation around the central C=O group is such that the C=O bond vector forms a larger angle to the plane of the naphthalene ring system than to the plane of the benzene ring, viz. 60.91 (16)° versus 13.94 (16)°. In the crystal structure, two π-π inter-actions formed between the naphthalene ring systems [centroid-centroid distances of 3.8014 (13) and 3.9823 (13) Å] and inter-molecular O-H⋯O and C-H⋯O hydrogen bonds are present.

No MeSH data available.


The arrangement of the molecules in the crystal structure, viewed in an oblique direction. van der Waals interactions and π– π interactions are shown as dashed lines.
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Fap3: The arrangement of the molecules in the crystal structure, viewed in an oblique direction. van der Waals interactions and π– π interactions are shown as dashed lines.


(8-Bromo-2-hydroxy-7-methoxy-1-naph-thyl)(4-chlorobenzoyl)methanone.

Mitsui R, Nakaema K, Nagasawa A, Noguchi K, Yonezawa N - Acta Crystallogr Sect E Struct Rep Online (2010)

The arrangement of the molecules in the crystal structure, viewed in an oblique direction. van der Waals interactions and π– π interactions are shown as dashed lines.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2983574&req=5

Fap3: The arrangement of the molecules in the crystal structure, viewed in an oblique direction. van der Waals interactions and π– π interactions are shown as dashed lines.
Bottom Line: In the title compound, C(18)H(12)BrClO(3), the naphthalene ring system and the benzene ring make a dihedral angle of 82.18 (9)°.The conformation around the central C=O group is such that the C=O bond vector forms a larger angle to the plane of the naphthalene ring system than to the plane of the benzene ring, viz. 60.91 (16)° versus 13.94 (16)°.In the crystal structure, two π-π inter-actions formed between the naphthalene ring systems [centroid-centroid distances of 3.8014 (13) and 3.9823 (13) Å] and inter-molecular O-H⋯O and C-H⋯O hydrogen bonds are present.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the title compound, C(18)H(12)BrClO(3), the naphthalene ring system and the benzene ring make a dihedral angle of 82.18 (9)°. The conformation around the central C=O group is such that the C=O bond vector forms a larger angle to the plane of the naphthalene ring system than to the plane of the benzene ring, viz. 60.91 (16)° versus 13.94 (16)°. In the crystal structure, two π-π inter-actions formed between the naphthalene ring systems [centroid-centroid distances of 3.8014 (13) and 3.9823 (13) Å] and inter-molecular O-H⋯O and C-H⋯O hydrogen bonds are present.

No MeSH data available.