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Bis{N,N,N-trimethyl-2-oxo-2-[2-(2,3,4- trihydroxy-benzyl-idene)hydrazin-yl]ethanaminium} tetra-chlorido-zincate(II) methanol solvate.

Novaković SB, Drašković BM, Vojinović-Ješić LS, Cešljević VI, Leovac VM - Acta Crystallogr Sect E Struct Rep Online (2010)

Bottom Line: These components are inter-connected in the crystal structure by an extensive network of O-H⋯O, N-H⋯O, C-H⋯O, O-H⋯N, O-H⋯Cl, N-H⋯Cl and C-H⋯Cl hydrogen bonds.The shortest inter-molecular inter-action is realized between the cation and anion [H⋯Cl = 2.29 (5) Å; O-H⋯Cl = 167 (3)°].C-H⋯O inter-actions also play a important role in the inter-connection of the cations.

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ABSTRACT
The asymmetric unit of the title compound, (C(12)H(18)N(3)O(4))(2)[ZnCl(4)]·CH(3)OH, consists of two Girard reagent-based cations, a tetra-chlorido-zincate anion and a mol-ecule of methanol as solvate. These components are inter-connected in the crystal structure by an extensive network of O-H⋯O, N-H⋯O, C-H⋯O, O-H⋯N, O-H⋯Cl, N-H⋯Cl and C-H⋯Cl hydrogen bonds. The shortest inter-molecular inter-action is realized between the cation and anion [H⋯Cl = 2.29 (5) Å; O-H⋯Cl = 167 (3)°]. C-H⋯O inter-actions also play a important role in the inter-connection of the cations.

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Related in: MedlinePlus

The molecular structure of title compound with atom labels. Displacement ellipsoids are drawn at 50% probability level. H atoms are presented as a small spheres of arbitrary radius. The intramolecular H-bonds are indicated as dashed lines.
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Fap1: The molecular structure of title compound with atom labels. Displacement ellipsoids are drawn at 50% probability level. H atoms are presented as a small spheres of arbitrary radius. The intramolecular H-bonds are indicated as dashed lines.


Bis{N,N,N-trimethyl-2-oxo-2-[2-(2,3,4- trihydroxy-benzyl-idene)hydrazin-yl]ethanaminium} tetra-chlorido-zincate(II) methanol solvate.

Novaković SB, Drašković BM, Vojinović-Ješić LS, Cešljević VI, Leovac VM - Acta Crystallogr Sect E Struct Rep Online (2010)

The molecular structure of title compound with atom labels. Displacement ellipsoids are drawn at 50% probability level. H atoms are presented as a small spheres of arbitrary radius. The intramolecular H-bonds are indicated as dashed lines.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2983568&req=5

Fap1: The molecular structure of title compound with atom labels. Displacement ellipsoids are drawn at 50% probability level. H atoms are presented as a small spheres of arbitrary radius. The intramolecular H-bonds are indicated as dashed lines.
Bottom Line: These components are inter-connected in the crystal structure by an extensive network of O-H⋯O, N-H⋯O, C-H⋯O, O-H⋯N, O-H⋯Cl, N-H⋯Cl and C-H⋯Cl hydrogen bonds.The shortest inter-molecular inter-action is realized between the cation and anion [H⋯Cl = 2.29 (5) Å; O-H⋯Cl = 167 (3)°].C-H⋯O inter-actions also play a important role in the inter-connection of the cations.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
The asymmetric unit of the title compound, (C(12)H(18)N(3)O(4))(2)[ZnCl(4)]·CH(3)OH, consists of two Girard reagent-based cations, a tetra-chlorido-zincate anion and a mol-ecule of methanol as solvate. These components are inter-connected in the crystal structure by an extensive network of O-H⋯O, N-H⋯O, C-H⋯O, O-H⋯N, O-H⋯Cl, N-H⋯Cl and C-H⋯Cl hydrogen bonds. The shortest inter-molecular inter-action is realized between the cation and anion [H⋯Cl = 2.29 (5) Å; O-H⋯Cl = 167 (3)°]. C-H⋯O inter-actions also play a important role in the inter-connection of the cations.

No MeSH data available.


Related in: MedlinePlus