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Poly[[aqua-[μ-1,4-bis-(3-pyridylmeth-yl)piperazine-κN:N'](μ-isophthalato-κO:O)copper(II)].

Gandolfo CM, Laduca RL - Acta Crystallogr Sect E Struct Rep Online (2010)

Bottom Line: The pseudo three-dimensional structure of the title compound is fostered by inter-layer O-H⋯O hydrogen bonding between the aqua ligands and unligated isophthalate O atoms.The selected crystal was non-merohedrally twinned.Only reflections from the major twin component were used in the solution and refinement.

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Affiliation: Lyman Briggs College, Department of Chemistry, Michigan State University, East Lansing, MI 48825 USA.

ABSTRACT
In the title compound, [Cu(C(8)H(4)O(4))(C(16)H(20)N(4))(H(2)O)](n), square-pyramidally coordinated Cu(II) ions are linked into [Cu(H(2)O)(isophthalate)](n) coordination polymer chains by isophthalate dianions. These chains are connected into undulating [Cu(H(2)O)(isophthalate)(3-bpmp)](n) [3-bmp is bis-(3-pyridylmeth-yl)piperazine] layers by 3-bpmp tethering ligands. The pseudo three-dimensional structure of the title compound is fostered by inter-layer O-H⋯O hydrogen bonding between the aqua ligands and unligated isophthalate O atoms. The selected crystal was non-merohedrally twinned. Only reflections from the major twin component were used in the solution and refinement.

No MeSH data available.


Stacking diagram for the title compound, viewed down the b axis.
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Fap3: Stacking diagram for the title compound, viewed down the b axis.


Poly[[aqua-[μ-1,4-bis-(3-pyridylmeth-yl)piperazine-κN:N'](μ-isophthalato-κO:O)copper(II)].

Gandolfo CM, Laduca RL - Acta Crystallogr Sect E Struct Rep Online (2010)

Stacking diagram for the title compound, viewed down the b axis.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2983567&req=5

Fap3: Stacking diagram for the title compound, viewed down the b axis.
Bottom Line: The pseudo three-dimensional structure of the title compound is fostered by inter-layer O-H⋯O hydrogen bonding between the aqua ligands and unligated isophthalate O atoms.The selected crystal was non-merohedrally twinned.Only reflections from the major twin component were used in the solution and refinement.

View Article: PubMed Central - HTML - PubMed

Affiliation: Lyman Briggs College, Department of Chemistry, Michigan State University, East Lansing, MI 48825 USA.

ABSTRACT
In the title compound, [Cu(C(8)H(4)O(4))(C(16)H(20)N(4))(H(2)O)](n), square-pyramidally coordinated Cu(II) ions are linked into [Cu(H(2)O)(isophthalate)](n) coordination polymer chains by isophthalate dianions. These chains are connected into undulating [Cu(H(2)O)(isophthalate)(3-bpmp)](n) [3-bmp is bis-(3-pyridylmeth-yl)piperazine] layers by 3-bpmp tethering ligands. The pseudo three-dimensional structure of the title compound is fostered by inter-layer O-H⋯O hydrogen bonding between the aqua ligands and unligated isophthalate O atoms. The selected crystal was non-merohedrally twinned. Only reflections from the major twin component were used in the solution and refinement.

No MeSH data available.