Limits...
Aqua-(9,10-dioxoanthracene-1,5-disul-fonato-κO)bis-(1,10-phenanthroline-κN,N')nickel(II).

Cao YY - Acta Crystallogr Sect E Struct Rep Online (2010)

Bottom Line: An intra-molecular O-H⋯O hydrogen bond occurs.In the crystal, inter-molecular O-H⋯O hydrogen bonds link the mononuclear complexes into chains extending parallel to [010].Furthermore, π-π stacking inter-actions [centroid-centroid distance = 3.5696 (6) Å] stabilize the crystal structuure.

View Article: PubMed Central - HTML - PubMed

Affiliation: Key Laboratory for Green Chemical Technology of the Ministry of Education, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, People's Republic of China and College of Chemistry and Life Science, Tianjin Normal University, Tianjin 300387, People's Republic of China.

ABSTRACT
In the mononuclear title complex, [Ni(C(14)H(6)O(8)S(2))(C(12)H(8)N(2))(2)(H(2)O)], the Ni(II) atom is in a distorted octa-hedral coordination formed by four N atoms from two chelating 1,10-phenanthroline ligands and by two O atoms, one from a 9,10-dioxoanthracene-1,5-disulfonate ligand and the other from a water mol-ecule. An intra-molecular O-H⋯O hydrogen bond occurs. In the crystal, inter-molecular O-H⋯O hydrogen bonds link the mononuclear complexes into chains extending parallel to [010]. Furthermore, π-π stacking inter-actions [centroid-centroid distance = 3.5696 (6) Å] stabilize the crystal structuure.

No MeSH data available.


two-dimensional supramolecular nework of I formed by hydrogen-bonding and π–π stacking interactions.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
getmorefigures.php?uid=PMC2983167&req=5

Fap2: two-dimensional supramolecular nework of I formed by hydrogen-bonding and π–π stacking interactions.


Aqua-(9,10-dioxoanthracene-1,5-disul-fonato-κO)bis-(1,10-phenanthroline-κN,N')nickel(II).

Cao YY - Acta Crystallogr Sect E Struct Rep Online (2010)

two-dimensional supramolecular nework of I formed by hydrogen-bonding and π–π stacking interactions.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2983167&req=5

Fap2: two-dimensional supramolecular nework of I formed by hydrogen-bonding and π–π stacking interactions.
Bottom Line: An intra-molecular O-H⋯O hydrogen bond occurs.In the crystal, inter-molecular O-H⋯O hydrogen bonds link the mononuclear complexes into chains extending parallel to [010].Furthermore, π-π stacking inter-actions [centroid-centroid distance = 3.5696 (6) Å] stabilize the crystal structuure.

View Article: PubMed Central - HTML - PubMed

Affiliation: Key Laboratory for Green Chemical Technology of the Ministry of Education, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, People's Republic of China and College of Chemistry and Life Science, Tianjin Normal University, Tianjin 300387, People's Republic of China.

ABSTRACT
In the mononuclear title complex, [Ni(C(14)H(6)O(8)S(2))(C(12)H(8)N(2))(2)(H(2)O)], the Ni(II) atom is in a distorted octa-hedral coordination formed by four N atoms from two chelating 1,10-phenanthroline ligands and by two O atoms, one from a 9,10-dioxoanthracene-1,5-disulfonate ligand and the other from a water mol-ecule. An intra-molecular O-H⋯O hydrogen bond occurs. In the crystal, inter-molecular O-H⋯O hydrogen bonds link the mononuclear complexes into chains extending parallel to [010]. Furthermore, π-π stacking inter-actions [centroid-centroid distance = 3.5696 (6) Å] stabilize the crystal structuure.

No MeSH data available.