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1-(4-Fluoro-phen-yl)biguanid-1-ium chloride.

Tutughamiarso M, Bolte M - Acta Crystallogr Sect E Struct Rep Online (2010)

Bottom Line: The title compound, C(8)H(11)FN(5) (+)·Cl(-), crystallized with a monoprotonated 1-(4-fluoro-phen-yl)biguanidinium cation and a chloride anion in the asymmetric unit.The biguanidium group is not planar [dihedral angle between the two CN(3) groups = 52.0 (1)°] and is rotated with respect to the phenyl group [τ = 54.3 (3)°].In the crystal, N-H⋯N hydrogen-bonded centrosymmetric dimers are connected into ribbons, which are further stabilized by N-H⋯Cl interactions, forming a three-dimensional hydrogen-bonded network.

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ABSTRACT
The title compound, C(8)H(11)FN(5) (+)·Cl(-), crystallized with a monoprotonated 1-(4-fluoro-phen-yl)biguanidinium cation and a chloride anion in the asymmetric unit. The biguanidium group is not planar [dihedral angle between the two CN(3) groups = 52.0 (1)°] and is rotated with respect to the phenyl group [τ = 54.3 (3)°]. In the crystal, N-H⋯N hydrogen-bonded centrosymmetric dimers are connected into ribbons, which are further stabilized by N-H⋯Cl interactions, forming a three-dimensional hydrogen-bonded network.

No MeSH data available.


A perspective view of the title compound, showing the atom-numbering scheme. Displacement ellipsoids are drawn at the 50% probability level and H atoms are shown as small spheres of arbitrary radii. The dashed line indicates the N—H···Cl- interactions.
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Fap1: A perspective view of the title compound, showing the atom-numbering scheme. Displacement ellipsoids are drawn at the 50% probability level and H atoms are shown as small spheres of arbitrary radii. The dashed line indicates the N—H···Cl- interactions.


1-(4-Fluoro-phen-yl)biguanid-1-ium chloride.

Tutughamiarso M, Bolte M - Acta Crystallogr Sect E Struct Rep Online (2010)

A perspective view of the title compound, showing the atom-numbering scheme. Displacement ellipsoids are drawn at the 50% probability level and H atoms are shown as small spheres of arbitrary radii. The dashed line indicates the N—H···Cl- interactions.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2983160&req=5

Fap1: A perspective view of the title compound, showing the atom-numbering scheme. Displacement ellipsoids are drawn at the 50% probability level and H atoms are shown as small spheres of arbitrary radii. The dashed line indicates the N—H···Cl- interactions.
Bottom Line: The title compound, C(8)H(11)FN(5) (+)·Cl(-), crystallized with a monoprotonated 1-(4-fluoro-phen-yl)biguanidinium cation and a chloride anion in the asymmetric unit.The biguanidium group is not planar [dihedral angle between the two CN(3) groups = 52.0 (1)°] and is rotated with respect to the phenyl group [τ = 54.3 (3)°].In the crystal, N-H⋯N hydrogen-bonded centrosymmetric dimers are connected into ribbons, which are further stabilized by N-H⋯Cl interactions, forming a three-dimensional hydrogen-bonded network.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
The title compound, C(8)H(11)FN(5) (+)·Cl(-), crystallized with a monoprotonated 1-(4-fluoro-phen-yl)biguanidinium cation and a chloride anion in the asymmetric unit. The biguanidium group is not planar [dihedral angle between the two CN(3) groups = 52.0 (1)°] and is rotated with respect to the phenyl group [τ = 54.3 (3)°]. In the crystal, N-H⋯N hydrogen-bonded centrosymmetric dimers are connected into ribbons, which are further stabilized by N-H⋯Cl interactions, forming a three-dimensional hydrogen-bonded network.

No MeSH data available.